Anderson impurity model
Hamiltonian used in quantum physics
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Through Metal and Spin (physics)
- ,
where the operator is the annihilation operator of a conduction electron, and is the annihilation operator for the impurity, is the conduction electron wavevector, labels the spin. The unperturbed single-electron energy, relative to the Fermi level, is for the conduction electrons and for impurity electrons. The The on–site Coulomb repulsion is , and gives the hybridization.
Regimes
The model yields several regimes that depend on the relationship of the impurity energy levels to the Fermi level :
- The empty orbital regime for , and the full orbital regime for , which have no local moment.
- The intermediate regime for or .
- The local moment regime for , which yields a magnetic moment at the impurity.
In the local moment regime, the magnetic moment is present at the impurity site. However, for low enough temperature, the moment is Kondo screened to give non-magnetic many-body singlet state.
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Heavy-fermion systems
For heavy-fermion systems, a lattice of impurities is described by the periodic Anderson model. The one-dimensional model is
- ,
where is the position of impurity site , and is the impurity creation operator (used instead of by convention for heavy-fermion systems). The hybridization term allows f-orbital electrons in heavy fermion systems to interact, although they are separated by a distance greater than the Hill limit.
Other variants
There are other variants of the Anderson model, such as the SU(4) Anderson model, which is used to describe impurities which have an orbital, as well as a spin, degree of freedom. This is relevant in carbon nanotube quantum dot systems. The SU(4) Anderson model Hamiltonian is
- ,
where and label the orbital degree of freedom (which can take one of two values), and represents the number operator for the impurity.

