Apophyllite
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Though relatively unfamiliar to the general public, apophyllites are fairly prevalent around the world, with specimens coming from some of the world's most well-known mineral localities. These localities include: Jalgaon, India; the Harz Mountains of Germany, Mont Saint-Hilaire in Canada, and Kongsberg, Norway, with other locations in Scotland, Ireland, Brazil, Japan, and throughout the United States.
Structure
Apophyllite has an unusual structure for a phyllosilicate. Whereas most phyllosilicates have a T layer (silica backbone) consisting of interlocked 6-fold rings of silica tetrahedra, with pseudohexagonal symmetry, the T layer in apophyllite consists of interlocked 4-fold and 8-fold rings of silica tetrahedra with true tetragonal symmetry.
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Species
- Fluorapophyllite-(K) (formerly fluorapophyllite, apophyllite-(KF)), KCa4Si8O20(F,OH)·8H2O – white, colorless, yellow, green, violet
- Hydroxyapophyllite-(K) (formerly hydroxyapophyllite, apophyllite-(KOH)), KCa4Si8O20(OH,F)·8H2O – white, colorless
- Fluorapophyllite-(Na) (formerly natroapophyllite, apophyllite-(NaF)), NaCa4Si8O20F·8H2O – brown, yellow, colorless
- Fluorapophyllit-(Cs) (new) CsCa4(Si8O20)F·8H2O
- Fluorapophyllit-(NH4) (new) NH4Ca4(Si8O20)F⋅8H2O

