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Bushveld Igneous Complex

Large early layered igneous intrusion

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Through Erosion and Iron

Located in South Africa, the BIC contains some of the richest ore deposits on Earth. It contains the world's largest reserves of platinum-group metals (PGMs) and platinum group elements (PGEs) — platinum, palladium, osmium, iridium, rhodium and ruthenium — along with vast quantities of iron, tin, chromium, titanium and vanadium. These are used in, but not limited to, jewellery, automobiles and electronics. Gabbro or norite is also quarried from parts of the complex and rendered into dimension stone. There have been more than 20 mine operations. There have been studies of potential uranium deposits. The complex is well known for its chromitite reef deposits, particularly the Merensky reef and the UG2 reef. It represents about 75 percent of the world's platinum and about 50 percent of the world's palladium resources. In this respect, the Bushveld complex is unique and one of the most economically significant mineral deposit complexes in the world.

Geology

Origin and formation

The Bushveld Igneous Complex covers a pear-shaped area in the central Transvaal. It is divided into an eastern and western lobe, with a further northern extension.

All three sections of the system were formed around the same time—about 2 billion years ago—and are remarkably similar. Vast quantities of molten rock from Earth's mantle were brought to the surface through long vertical cracks in Earth's crust—huge arcuate differentiated lopolithic intrusions—creating the geological intrusion known as the Bushveld Igneous Complex.

These intrusions are thought to predate the nearby Vredefort impact to the south, by some 30 million years. The effects of these injections of molten rock over time, combined with the crystallisation of different minerals at different temperatures, resulted in the formation of a structure rather like a layered cake consisting of distinct rock strata, including three PGM-bearing layers, referred to as reefs. Large portions of the central area are covered by younger rocks.

The extrusions were emplaced over an early diabasic sill, outcrops of which are visible on the southeastern side of the Complex. These are typically greenish in colour and composed of clinopyroxene, altered to hornblende and plagioclase, and are regarded as the earliest phase of the Complex.

The Complex includes layered mafic intrusions (the Rustenburg Layered Suite) and a felsic phase. The complex has its geographic centre located north of Pretoria in South Africa at about 25° S and 29° E. It covers over 66,000 km2 (25,000 sq mi), an area the size of Ireland.

The complex varies in thickness, in places reaching 9 kilometres (5.6 mi) thick. Lithologies vary from largely ultramafic peridotite, chromitite, harzburgite, and bronzitite in the lower sections to mafic norite, anorthosite, and gabbro toward the top, and the mafic Rustenburg Layered Suite is followed by a felsic phase (the Lebowa Granite Suite).

The orebodies within the complex include the UG2 (Upper Group 2) reef containing up to 43.5% chromite, and the platinum-bearing horizons Merensky Reef and Platreef. The Merensky Reef varies from 30 to 90 cm in thickness. It is a norite with extensive chromitite and sulfide layers or zones containing the ore.

The Reef contains an average of 10 ppm platinum group metals in pyrrhotite, pentlandite, and pyrite as well as in rare platinum group minerals and alloys. The Merensky and UG2 reefs contain approximately 90% of the world's known PGM reserves. About 80% of the platinum and 20% of the palladium mined each year are produced from these horizons.

Proposed mechanisms of formation

The formation mechanisms of the chromitite seams in the Bushveld Igneous Complex are highly debated: numerous mechanisms have been proposed. The following is a non-exhaustive list of chromitite formations process.

  • Changes in chemical and physical properties causes the magma to become concentrated in chromite. When this happens the liquidus becomes free from any other phases. Therefore, chromite is the only mineral to crystallize in the melt thus, accumulating in monomineralic layers on the floor of the magma chamber.
  • Increase in total pressure of the system, oxygen fugacity and alpha-silica.
  • One of the most accepted mechanisms were proposed by Irvine: it is suggested the chromitites may have formed when a chemically primitive magma intruded into an existing chamber to mix with a differentiated magma.
  • Gravity and size controlled settling and separation of chromite (concurring with olivine and OPX) grains within crystal-rich slurries
  • The mixing of resident magma and granitic melts derived from fusible country rocks
  • Mixing of ultramafic magma of layered intrusions, with magma parental to anorthosites
  • Deformation of the magma chamber, nucleation, ascent and expansion of gas bubbles or the emplacement of a new pulse of magma increasing total pressure conditions.
  • An increase in oxygen fugacity of the magma within the chamber possibly through the release of gas pressure, differential diffusion of hydrogen, or loss of gasses by diffusion.
  • Absorption of water by the magma

There has been a proposal of the origins of at least three different processes used to model the PGE mineralization in the area:

  • Collection by the sulphide liquids, due to the PGE's affinity toward a sulphide melt
  • Directly crystallised from a silicate magma, and then collected by oxide minerals
  • Concentration by hydrothermal and or hydromagmatic fluids

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