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Feshbach resonance

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Through Physics, Atom and Dissociation (chemistry)

Feshbach resonances have become important in the study of cold atoms systems, including Fermi gases and Bose–Einstein condensates (BECs). In the context of scattering processes in many-body systems, the Feshbach resonance occurs when the energy of a bound state of an interatomic potential is equal to the kinetic energy of a colliding pair of atoms. In experimental settings, the Feshbach resonances provide a way to vary interaction strength between atoms in the cloud by changing scattering length, asc, of elastic collisions. For atomic species that possess these resonances (like K39 and K40), it is possible to vary the interaction strength by applying a uniform magnetic field. Among many uses, this tool has served to explore the transition from a BEC of fermionic molecules to weakly interacting fermion-pairs the BCS in Fermi clouds. For the BECs, Feshbach resonances have been used to study a spectrum of systems from the non-interacting ideal Bose gases to the unitary regime of interactions.

Introduction

Consider a general quantum scattering event between two particles. In this reaction, there are two reactant particles denoted by A and B, and two product particles denoted by A' and B' . For the case of a reaction (such as a nuclear reaction), we may denote this scattering event by

A+B→A′+B′ or A(B,B′)A′.

The combination of the species and quantum states of the two reactant particles before or after the scattering event is referred to as a reaction channel. Specifically, the species and states of A and B constitute the entrance channel, while the types and states of A' and B' constitute the exit channel. An energetically accessible reaction channel is referred to as an open channel, whereas a reaction channel forbidden by energy conservation is referred to as a closed channel.

Consider the interaction of two particles A and B in an entrance channel C. The positions of these two particles are given by r→A and r→B, respectively. The interaction energy of the two particles will usually depend only on the magnitude of the separation R≡|r→A−r→B|, and this function, sometimes referred to as a potential energy curve, is denoted by Vc(R). Often, this potential will have a pronounced minimum and thus admit bound states.

The total energy of the two particles in the entrance channel is

E=T+Vc(R)+Δ(P→),

where T denotes the total kinetic energy of the relative motion (center-of-mass motion plays no role in the two-body interaction), Δ is the contribution to the energy from couplings to external fields, and P→ represents a vector of one or more parameters such as magnetic field or electric field. We consider now a second reaction channel, denoted by D, which is closed for large values of R. Let this potential curve VD(R) admit a bound state with energy ED.

A Feshbach resonance occurs when

ED≈T+Vc(R)+Δ(P→0)

for some range of parameter vectors {P→0}. When this condition is met, then any coupling between channel C and channel D can give rise to significant mixing between the two channels; this manifests itself as a drastic dependence of the outcome of the scattering event on the parameter or parameters that control the energy of the entrance channel. These couplings can arise from spin-exchange interactions or relativistic spin-dependent interactions.

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