Greenhouse gas monitoring

Methodology

Carbon dioxide monitoring

Manometry

Manometry is a key measurement tool for atmospheric carbon dioxide by first measuring the volume, temperature, and pressure of a particular amount of dry air. The air sample is dried by passing it through multiple dry ice traps and then collecting it in a five-liter vessel. The temperature is taken via a thermometer and pressure is calculated using manometry. Then, liquid nitrogen is added, causing the carbon dioxide to condense and become measurable by volume. The ideal gas law is accurate to 0.3% in these pressure conditions.

Infrared gas analyzer

Infrared analyzers were used at Mauna Loa Observatory and at Scripps Institution of Oceanography between 1958 and 2006. IR analyzers operate by pumping an unknown sample of dry air through a 40 cm long cell. A reference cell contains dry carbon dioxide-free air. A glowing nichrome filament radiates broadband IR radiation which splits into two beams and passes through the gas cells. Carbon dioxide absorbs some of the radiation, allowing more radiation that passes through the reference cell to reach the detector than radiation passing through the sample cell. Data is collected on a strip chart recorder. The concentration of carbon dioxide in the sample is quantified by calibrating with a standard gas of known carbon dioxide content.

Titrimetry

Titrimetry is another method of measuring atmospheric carbon dioxide that was first used by a Scandinavian group at 15 different ground stations. They began passing a 100.0 mL air sample through a solution of barium hydroxide containing cresolphthalein indicator.

Methane gas monitoring

Differential absorption lidar

Range-resolved infrared differential absorption lidar (DIAL) is a means of measuring methane emissions from various sources, including active and closed landfill sites. The DIAL takes vertical scans above methane sources and then spatially separates the scans to accurately measure the methane emissions from individual sources. Measuring methane emissions is a crucial aspect of climate change research, as methane is among the most impactful gaseous hydrocarbon species.

Nitrous oxide monitoring

Atmospheric Chemistry Experiment‐Fourier Transform Spectrometer (ACE-FTS)

Nitrous oxide is one of the most prominent anthropogenic ozone-depleting gases in the atmosphere. It is released into the atmosphere primarily through natural sources such as soil and rock, as well as anthropogenic processes like farming. Atmospheric nitrous oxide is also created in the atmosphere as a product of a reaction between nitrogen and electronically excited ozone in the lower thermosphere.

The Atmospheric Chemistry Experiment‐Fourier Transform Spectrometer (ACE-FTS) is a tool used for measuring nitrous oxide concentrations in the upper to lower troposphere. This instrument, which is attached to the Canadian satellite SCISAT, has shown that nitrous oxide is present throughout the entire atmosphere during all seasons, primarily due to energetic particle precipitation. Measurements taken by the instrument show that different reactions create nitrous oxide in the lower thermosphere than in the mid to upper mesosphere. The ACE-FTS is a crucial resource in predicting future ozone depletion in the upper stratosphere by comparing the different ways in which nitrous oxide is released into the atmosphere.