Grid complex
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Through Ligand
Nomenclature
The nomenclature is based on [n × m] G, n corresponds to the number of ligands above the metal ion level, m the number below ones. In case of using only one ligand type, the homoleptic grid is formed in a square [nxn] structure. When using different ligands arise heteroleptic complexes, however, compete with the homoleptic. The number of metal ions is always n + m.
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Application
The grid complexes exhibit pH-dependent changes in the optical absorption, electronic spin states and reversible redox states. The latticial metal complexes may thus be used theoretically for information storage and processing in the future.
Other uses
An interwoven grid complex has been used to template the synthesis of a doubly-twisted [2]catenane (otherwise known as a Solomon Link). The unique arrangement of interwoven ligands around the planar array of iron, zinc, or cobalt ions generated the crossing points required to covalently trap the interlocked structure using ring-closing metathesis. Building on this discovery, 2 × 2 interwoven grids were used to template the synthesis of more topologically complex molecules: a six-crossing doubly-interlocked [2]catenane and a granny knot. In 2021, the first report of a 3 × 3 interwoven grid was published. It was used to template the synthesis of a molecular Endless Knot.