Hydrogen thioperoxide
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Through Sulfur, Organic compound and Oxidation state
Formation
Hydrogen thioperoxide has been synthesized in labs by photolysis of a mixture of ozone and hydrogen sulfide frozen in argon at 8 K and by pyrolysis of di-tert-butyl sulfoxide. Yet another synthesis is by an electric discharge through water and sulfur.
In the interstellar medium there is a hypothesis that hydrogen thioperoxide is formed in a reaction of sulfur monoxide with the trihydrogen cation, dihydrogen and an electron. Another possible route, is sulfur monoxide reacting with atomic hydrogen to form HOS and HSO which in turn can add another hydrogen atom. However this mechanism probably needs a dust grain to take away excess energy.
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Properties
Hydrogen thioperoxide molecules have a gauche conformation. They are unsymmetrical, but have a low barrier to convert from left-hand to right-hand forms, so that the molecule can tunnel between the forms.
The measurements of the bond-lengths in hydrogen thioperoxide are H–S 1.3420 Å, S–O 1.6616 Å, O–H 0.9606 Å. The bond angles are H–S–O 98.57°, S–O–H 107.19°. The H–S and O–H bonds are twisted at 90.41°.
The half-life of hydrogen thioperoxide in water is 40 minutes, much longer than the expected half-life of less than seconds for a sulfenic acid.
Reactions
Two molecules of hydrogen thioperoxide can undergo cyclocondensation to form sulfinothioic acid HS(=O)SH and water.
Hydrosulfide HS− can react with HSOH to yield disulfane HSSH.