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Krypton fluoride laser

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  • 4 chapters

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Through Coordination complex, Spectrum and Joule

KrF and ArF excimer lasers are widely incorporated into high-resolution photolithography machines, one of the critical tools required for microelectronic chip manufacturing in nanometer dimensions. Excimer laser lithography has enabled transistor feature sizes to shrink from 800 nanometers in 1990 to 10 nanometers in 2016.

Theory

A krypton fluoride laser absorbs energy from a source, causing the krypton gas to react with the fluorine gas producing the exciplex krypton fluoride, a temporary complex in an excited energy state:

2 Kr + F
2 → 2 KrF

The complex can undergo spontaneous or stimulated emission, reducing its energy state to a metastable, but highly repulsive ground state. The ground state complex quickly dissociates into unbound atoms:

2 KrF → 2 Kr + F
2

The result is an exciplex laser which radiates energy at 248 nm, near the ultraviolet portion of the spectrum, corresponding with the energy difference between the ground state and the excited state of the complex.

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