Lably
Skip to content

Magnetic anisotropy

  • 3 min read
  • 2 chapters

Related on Lably

Through Magnetism, Magnetic field and Benzene

For most magnetically anisotropic materials, there are two easiest directions to magnetize the material, which are a 180° rotation apart. The line parallel to these directions is called the easy axis. In other words, the easy axis is an energetically favorable direction of spontaneous magnetization. Because the two opposite directions along an easy axis are usually equivalently easy to magnetize along, the actual direction of magnetization can just as easily settle into either direction, which is an example of spontaneous symmetry breaking.

Magnetic anisotropy is a prerequisite for hysteresis in ferromagnets: without it, a ferromagnet is superparamagnetic.

At the molecular level

The magnetic anisotropy of a benzene ring (A), alkene (B), carbonyl (C), alkyne (D), and a more complex molecule (E) are shown in the figure. Each of these unsaturated functional groups (A-D) create a tiny magnetic field and hence some local anisotropic regions (shown as cones) in which the shielding effects and the chemical shifts are unusual. The bisazo compound (E) shows that the designated proton {H} can appear at different chemical shifts depending on the photoisomerization state of the azo groups. The trans isomer holds proton {H} far from the cone of the benzene ring thus the magnetic anisotropy is not present. While the cis form holds proton {H} in the vicinity of the cone, shields it and decreases its chemical shift. This phenomenon enables a new set of nuclear Overhauser effect (NOE) interactions (shown in red) that come to existence in addition to the previously existing ones (shown in blue).

Sign in to keep reading

One more chapter is free with a Lably account.

More in Physics