Methylene group

This stands in contrast to a situation where the carbon atom is bound to the rest of the molecule by a double bond, which is preferably called a methylidene group, represented =CH₂. Formerly the methylene name was used for both isomers. The name “methylene bridge“ can be used for the single-bonded isomer, to emphatically exclude methylidene. The distinction is often important, because the double bond is chemically different from two single bonds.

The methylene group should be distinguished from the CH₂ molecule called carbene. This was also formerly called methylene.

Activated methylene

The central carbon in 1,3-dicarbonyl compound is known as an activated methylene group. This is because, owing to the structure, the carbon is especially acidic and can easily be deprotonated to form a methylene group.