Polytelluride
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Through Chemistry, Transition metal and Coordination complex
Preparation
Conceptually, polytellurides are derived from polytelluranes H2Ten, but such neutral species are not known (even H2Te is labile). Instead, analogous to the preparation of many Zintl ions, polytellurides are produced by reduction of elemental Te with alkali metals. Such reactions can be conducted by heating a mixture of the solids or by dissolving Te metal in amine solvents of alkali metals. Once generated, these alkali metal polytellurides can be converted to lipophilic salts by treatment cryptand ligands or by ion exchange with quat salts.
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Structures
Salts of polytellurides have often been characterized by X-ray crystallography. Polytelluride salts generally feature open chains, which adopt a zig-zag conformation. In some cases, cyclic structures are observed as in Li2Te7, which features a square-planar Te center bound to two Te-Te-Te chains.
As ligands in coordination complexs, polytellurides are generally bidentate. Complexes of penta-, tetra-, and tritelluride ligands are known. One example is the spirocyclic [Zn(Te4)2]2-.