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Thorianite

Thorium oxide mineral

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Thorianite Locality: Ambatofotsy pegmatite, Mahavelona Commune, Soavinandriana District, Itasy Region , Antananarivo Province , Madagascar ( Locality at mindat.org ) A very aesthetic cluster of four,
Robert M. Lavinsky · CC BY-SA 3.0

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Chemistry

Based on color, specific gravity and composition three types of thorianite are distinguished:

  • α-thorianite
  • β-thorianite
  • γ-thorianite

Thorianite and uraninite form a complete solid solution series in synthetic and natural material. The division between the two species is at Th:U = 1:1 with uranium possibly making up to 46.50% and thorium ranging up to 87.88%. Rare earths, chiefly cerium, substitute for thorium in amounts up to 8% by mass. Cerium is probably present as Ce4+. Complete series is known in synthetic material between CeO2 - PrO2 - ThO2 - UO2. Small amounts of Fe3+ and zirconium also may be isomorphous with thorium. Lead present is probably radiogenic.

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