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Dyson series

Expansion of the time evolution operator

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Through Scattering and Data

This series diverges asymptotically, but in quantum electrodynamics (QED) at the second order the difference from experimental data is in the order of 10−10. This close agreement holds because the coupling constant (also known as the fine-structure constant) of QED is much less than 1.

Dyson operator

In the interaction picture, a Hamiltonian H, can be split into a free part H0 and an interacting part VS(t) as H = H0 + VS(t).

The potential in the interacting picture is

VI(t)=eiH0(t−t0)/ℏVS(t)e−iH0(t−t0)/ℏ,

where H0 is time-independent and VS(t) is the possibly time-dependent interacting part of the Schrödinger picture. To avoid subscripts, V(t) stands for VI(t) in what follows.

In the interaction picture, the evolution operator U is defined by the equation:

Ψ(t)=U(t,t0)Ψ(t0)

This is sometimes called the Dyson operator.

The evolution operator forms a unitary group with respect to the time parameter. It has the group properties:

  • Identity and normalization: U(t,t)=1,
  • Composition: U(t,t0)=U(t,t1)U(t1,t0),
  • Time Reversal: U−1(t,t0)=U(t0,t),
  • Unitarity: U†(t,t0)U(t,t0)=1

and from these is possible to derive the time evolution equation of the propagator:

iℏddtU(t,t0)Ψ(t0)=V(t)U(t,t0)Ψ(t0).

In the interaction picture, the Hamiltonian is the same as the interaction potential Hint=V(t) and thus the equation can also be written in the interaction picture as

iℏddtΨ(t)=HintΨ(t)

Caution: this time evolution equation is not to be confused with the Tomonaga–Schwinger equation.

The formal solution is

U(t,t0)=1−iℏ−1∫t0tdt1V(t1)U(t1,t0),

which is ultimately a type of Volterra integral.

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