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Sodium-ion battery

Type of rechargeable battery

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Through Rechargeable battery, Sodium and Electric charge

SIBs received academic and commercial interest in the 2010s and early 2020s, largely due to lithium's high cost, uneven geographic distribution, and environmentally damaging extraction process. Unlike lithium, sodium is abundant, particularly in saltwater. Further, cobalt, copper, and nickel are not required for many types of sodium-ion batteries as they are in Lithium batteries, and abundant iron-based materials (such as NaFeO
2 with the Fe3+/Fe4+ redox pair) work well in Na+ batteries. This is because the ionic radius of Na+ (116 pm) is substantially larger than that of Fe2+ and Fe3+ (69–92 pm depending on the spin state), whereas the ionic radius of Li+ is similar (90 pm). Similar ionic radii of lithium and iron allow them to mix in the cathode during battery cycling, costing cyclable charge. A downside of the larger ionic radius of Na+ is slower intercalation kinetics.

The modern development of Na+
batteries for production started in the 1990s. Companies such as HiNa and CATL in China, Faradion in the United Kingdom, Tiamat in France, Northvolt in Sweden, and Natron Energy in the US, claimed to be close to commercialization, employing sodium layered transition metal oxides (Na
xTMO
2), Prussian white (a Prussian blue analogue) or vanadium phosphate as cathode materials.

Sodium-ion accumulators are operational for fixed electrical grid storage, and vehicles with sodium-ion battery packs are commercially available for light scooters made by Yadea, which use HuaYu sodium-ion battery technology.

History

Sodium-ion battery development took place in the 1970s and early 1980s. However, by the 1990s, lithium-ion batteries had demonstrated more commercial promise, causing interest in sodium-ion batteries to decline. In the early 2010s, sodium-ion batteries experienced a resurgence, driven largely by the increasing cost of lithium-ion battery raw materials. Also, the number of patent families reached the number of non-patent publication after ca. 2020, which usually signify the fact that the technology reached the commercialization stage.

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