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Electromagnetic spectrum

Full range of electromagnetic radiation frequencies

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Radio waves, at the low-frequency end of the spectrum, have the lowest photon energy and the longest wavelengths—thousands of kilometers, or more. They can be emitted and received by antennas, and pass through the atmosphere, foliage, and most building materials.

Gamma rays, at the high-frequency end of the spectrum, have the highest photon energies and the shortest wavelengths—much smaller than an atomic nucleus. Gamma rays, X-rays, and extreme ultraviolet rays are called ionizing radiation because their high photon energy is able to ionize atoms, causing chemical reactions. Longer-wavelength radiation such as visible light is non-ionizing; the photons do not have sufficient energy to ionize atoms.

Throughout most of the electromagnetic spectrum, spectroscopy can be used to separate waves of different frequencies, so that the intensity of the radiation can be measured as a function of frequency or wavelength. Spectroscopy is used to study the interactions of electromagnetic waves with matter.

History and discovery

In 1672 Isaac Newton submitted his first paper to the Royal Society, describing the range of colours that white light could be split into with a prism using the term spectrum. Newton showed that these colours were intrinsic to light and could be combined to recreate white light. Around 1801, Thomas Young performed a number of interference experiments that played a major role in the acceptance of the wave theory of light.

In 1800, William Herschel discovered infrared radiation. He was studying the temperature of different colours by moving a thermometer through light split by a prism. He noticed that the highest temperature was beyond red. He theorized that this temperature change was due to "calorific rays", a type of light ray that could not be seen. The next year, Johann Ritter, working at the other end of the spectrum, noticed what he called "chemical rays" (invisible light rays that induced certain chemical reactions). These behaved similarly to visible violet light rays, but were beyond them in the spectrum. They were later renamed ultraviolet radiation.

The study of electromagnetism began in 1820 when Hans Christian Ørsted discovered that electric currents produce magnetic fields (Oersted's law). Light was first linked to electromagnetism in 1845, when Michael Faraday noticed that the polarization of light traveling through a transparent material responded to a magnetic field (see Faraday effect). During the 1860s, James Clerk Maxwell developed four partial differential equations (Maxwell's equations) for the electromagnetic field. Two of these equations predicted the possibility and behavior of waves in the field. Analyzing the speed of these theoretical waves, Maxwell realized that they must travel at a speed that was about the known speed of light. This startling coincidence in value led Maxwell to make the inference that light itself is a type of electromagnetic wave. Maxwell's equations predicted an infinite range of frequencies of electromagnetic waves, all traveling at the speed of light. This was the first indication of the existence of the entire electromagnetic spectrum.

Maxwell's predicted waves included waves at very low frequencies compared to infrared, which he hypothesized might be created by oscillating charges. Attempting to prove Maxwell's equations and detect such low frequency electromagnetic radiation, in 1886, the physicist Heinrich Hertz built an apparatus to generate and detect what are now called radio waves. Hertz found the waves and was able to infer (by measuring their wavelength and multiplying it by their frequency) that they traveled at the speed of light. Hertz also demonstrated that the new radiation could be both reflected and refracted by various dielectric media, in the same manner as light. For example, Hertz was able to focus the waves using a lens made of tree resin. In a later experiment, Hertz similarly produced and measured the properties of microwaves. These new types of waves paved the way for inventions such as the wireless telegraph and the radio.

In 1895, Wilhelm Röntgen noticed a new type of radiation emitted during an experiment with an evacuated tube subjected to a high voltage. He called this radiation "x-rays" and found that they were able to travel through parts of the human body but were reflected or stopped by denser matter such as bones. Before long, many uses were found for this radiography.

The last portion of the electromagnetic spectrum was filled in with the discovery of gamma rays. In 1900, Paul Villard was studying the radioactive emissions of radium when he identified a new type of radiation that he at first thought consisted of particles similar to known alpha and beta particles, but with the power of being far more penetrating than either. However, in 1910, British physicist William Henry Bragg demonstrated that gamma rays are electromagnetic radiation, not particles, and in 1914, Ernest Rutherford (who had named them gamma rays in 1903 when he realized that they were fundamentally different from charged alpha and beta particles) and Edward Andrade measured their wavelengths, and found that gamma rays were similar to X-rays, but with shorter wavelengths.

The wave-particle debate was rekindled in 1901 when Max Planck discovered that light is absorbed only in discrete "quanta", now called photons, implying that light has a particle nature. This idea was made explicit by Albert Einstein in 1905, but never accepted by Planck and many other contemporaries. The modern position of science is that electromagnetic radiation has both a wave and a particle nature, the wave-particle duality. The contradictions arising from this position are still being debated by scientists and philosophers.

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