Terahertz radiation

Terahertz gap

Until the 2008 manufacture of an EO (electro-optic) Dipole Dendrimer Excitation (DDE) emitter, no practical technologies existed for generating and detecting radiation in a frequency band in the THz region, known as the "terahertz gap". This gap has previously been defined as 0.1 to 10 THz (wavelengths of 3 mm to 30 μm) although the upper boundary is considered by some sources as 30 THz (a wavelength of 10 μm). Until the 2008 DDE implementation by Applied Research & Photonics (ARP) Inc., frequencies within the range from 0.1 to 30THz, useful power generation and receiver technologies were inefficient and unfeasible. Since 2008, ARP has commercially manufactured sub-nanometer resolution 3D Imaging & Spectroscopy tools, known as TeraSpectra.

Mass production of devices in this range and operation at room temperature (at which energy kT is equal to the energy of a photon with a frequency of 6.2 THz) are mostly impractical. This leaves a gap between mature microwave technologies in the highest frequencies of the radio spectrum and the well-developed optical engineering of infrared detectors in their lowest frequencies. This radiation is mostly used in small-scale, specialized applications such as submillimetre astronomy. Research that attempts to resolve this issue has been conducted since the late 20th century.

In 2024, an experiment was published by German researchers where a TDLAS experiment at 4.75 THz was performed in "infrared quality" with an uncooled pyroelectric receiver. The THz source was a cw DFB-QC-Laser operating at 43.3 K, with laser currents between 480 mA and 600 mA.

Closure of the terahertz gap

See DDE as exception to, "Most vacuum electronic devices that are used for microwave generation can be modified to operate at terahertz frequencies, including the magnetron, gyrotron, synchrotron, and free-electron laser. " Similarly, microwave detectors such as the tunnel diode have been re-engineered to detect at terahertz and infrared frequencies as well. However, many of these devices are in prototype form, are not compact, or exist at university or government research labs, without the benefit of cost savings due to mass production.

Research

Molecular biology

Terahertz radiation has comparable frequencies to the motion of biomolecular systems in the course of their function (a frequency 1THz is equivalent to a timescale of 1 picosecond, therefore in particular the range of hundreds of GHz up to low numbers of THz is comparable to biomolecular relaxation timescales of a few ps to a few ns). Modulation of biological and also neurological function is therefore possible using radiation in the range hundreds of GHz up to a few THz at relatively low energies (without significant heating or ionisation) achieving either beneficial or harmful effects.

Medical imaging

Unlike X-rays, terahertz radiation is not ionizing radiation and its low photon energies in general do not damage living tissues and DNA. Some frequencies of terahertz radiation can penetrate several millimeters of tissue with low water content (e.g., fatty tissue) and reflect back. Terahertz radiation can also detect differences in water content and density of a tissue. Such methods could allow effective detection of epithelial cancer with an imaging system that is safe, non-invasive, and painless. In response to the demand for COVID-19 screening terahertz spectroscopy and imaging has been proposed as a rapid screening tool.

The first images generated using terahertz radiation date from the 1960s; however, in 1995 images generated using terahertz time-domain spectroscopy generated a great deal of interest.

Some frequencies of terahertz radiation can be used for 3D imaging of teeth and may be more accurate than conventional X-ray imaging in dentistry.

Security

Terahertz radiation can penetrate fabrics and plastics, so it can be used in surveillance, such as security screening, to uncover concealed weapons on a person, remotely. This is of particular interest because many materials of interest have unique spectral "fingerprints" in the terahertz range. This offers the possibility to combine spectral identification with imaging. In 2002, the European Space Agency (ESA) Star Tiger team, based at the Rutherford Appleton Laboratory (Oxfordshire, UK), produced the first passive terahertz image of a hand. By 2004, ThruVision Ltd, a spin-out from the Council for the Central Laboratory of the Research Councils (CCLRC) Rutherford Appleton Laboratory, had demonstrated the world's first compact THz camera for security screening applications. The prototype system successfully imaged guns and explosives concealed under clothing. Passive detection of terahertz signatures avoid the bodily privacy concerns of other detection by being targeted to a very specific range of materials and objects.

In January 2013, the NYPD announced plans to experiment with the new technology to detect concealed weapons, prompting Miami blogger and privacy activist Jonathan Corbett to file a lawsuit against the department in Manhattan federal court that same month, challenging such use: "For thousands of years, humans have used clothing to protect their modesty and have quite reasonably held the expectation of privacy for anything inside of their clothing, since no human is able to see through them." He sought a court order to prohibit using the technology without reasonable suspicion or probable cause. By early 2017, the department said it had no intention of ever using the sensors given to them by the federal government.

Scientific use and imaging

In addition to its current use in submillimetre astronomy, terahertz radiation spectroscopy could provide new sources of information for chemistry and biochemistry.

Recently developed methods of THz time-domain spectroscopy (THz TDS) and THz tomography have been shown to be able to image samples that are opaque in the visible and near-infrared regions of the spectrum. The utility of THz-TDS is limited when the sample is very thin, or has a low absorbance, since it is very difficult to distinguish changes in the THz pulse caused by the sample from those caused by long-term fluctuations in the driving laser source or experiment. However, THz-TDS produces radiation that is both coherent and spectrally broad, so such images can contain far more information than a conventional image formed with a single-frequency source.

Submillimeter waves are used in physics to study materials in high magnetic fields, since at high fields (over about 11 tesla), the electron spin Larmor frequencies are in the submillimeter band. Many high-magnetic field laboratories perform these high-frequency EPR experiments, such as the National High Magnetic Field Laboratory (NHMFL) in Florida.

Terahertz radiation could let art historians see murals hidden beneath coats of plaster or paint in centuries-old buildings, without harming the artwork.

In additional, THz imaging has been done with lens antennas to capture radio image of the object.

Particle accelerators

New types of particle accelerators that could achieve multi Giga-electron volts per metre (GeV/m) accelerating gradients are of utmost importance to reduce the size and cost of future generations of high energy colliders as well as provide a widespread availability of compact accelerator technology to smaller laboratories around the world. Gradients in the order of 100 MeV/m have been achieved by conventional techniques and are limited by RF-induced plasma breakdown. Beam driven dielectric wakefield accelerators (DWAs) typically operate in the Terahertz frequency range, which pushes the plasma breakdown threshold for surface electric fields into the multi-GV/m range. DWA technique allows to accommodate a significant amount of charge per bunch, and gives an access to conventional fabrication techniques for the accelerating structures. To date 0.3 GeV/m accelerating and 1.3 GeV/m decelerating gradients have been achieved using a dielectric lined waveguide with sub-millimetre transverse aperture.

An accelerating gradient larger than 1 GeV/m, can potentially be produced by the Cherenkov Smith-Purcell radiative mechanism in a dielectric capillary with a variable inner radius. When an electron bunch propagates through the capillary, its self-field interacts with the dielectric material and produces wakefields that propagate inside the material at the Cherenkov angle. The wakefields are slowed down below the speed of light, as the relative dielectric permittivity of the material is larger than 1. The radiation is then reflected from the capillary's metallic boundary and diffracted back into the vacuum region, producing high accelerating fields on the capillary axis with a distinct frequency signature. In presence of a periodic boundary the Smith-Purcell radiation imposes frequency dispersion.

A preliminary study with corrugated capillaries has shown some modification to the spectral content and amplitude of the generated wakefields, but the possibility of using Smith-Purcell effect in DWA is still under consideration.

Communication

The high atmospheric absorption of terahertz waves limits the range of communication using existing transmitters and antennas to tens of meters. However, the huge unallocated bandwidth available in the band (ten times the bandwidth of the millimeter wave band, 100 times that of the SHF microwave band) makes it very attractive for future data transmission and networking use. There are tremendous difficulties to extending the range of THz communication through the atmosphere, but the world telecommunications industry is funding much research into overcoming those limitations. One promising application area is the 6G cellphone and wireless standard, which will supersede the current 5G standard around 2030. In particular, 6G is expected to leverage advanced technologies such as terahertz and full duplex (FD) communications, combined with dynamic spectrum sharing to meet the growing demand for higher data rates and more efficient spectrum efficiency.

For a given antenna aperture, the gain of directive antennas scales with the square of frequency, while for low power transmitters the power efficiency is independent of bandwidth. So the consumption factor theory of communication links indicates that, contrary to conventional engineering wisdom, for a fixed aperture it is more efficient in bits per second per watt to use higher frequencies in the millimeter wave and terahertz range. Small directive antennas a few centimeters in diameter can produce very narrow 'pencil' beams of THz radiation, and phased arrays of multiple antennas could concentrate virtually all the power output on the receiving antenna, allowing communication at longer distances.

In May 2012, a team of researchers from the Tokyo Institute of Technology published in Electronics Letters that it had set a new record for wireless data transmission by using T-rays and proposed they be used as bandwidth for data transmission in the future. The team's proof of concept device used a resonant tunneling diode (RTD) negative resistance oscillator to produce waves in the terahertz band. With this RTD, the researchers sent a signal at 542 GHz, resulting in a data transfer rate of 3 Gigabits per second. It doubled the record for data transmission rate set in November 2011. The study suggested that Wi-Fi using the system would be limited to approximately 10 metres (33 ft), but could allow data transmission at up to 100 Gbit/s. In 2011, Japanese electronic parts maker Rohm and a research team at Osaka University produced a chip capable of transmitting 1.5 Gbit/s using terahertz radiation. In 2017, researchers at Brown University were able to transfer two videos at a speed of 50 Gbit/s using a terahertz multiplexer, considerably faster than the transfer speed of contemporary cellular data networks.

Potential uses exist in high-altitude telecommunications, above altitudes where water vapor causes signal absorption: aircraft to satellite, or satellite to satellite.

Amateur radio

A number of administrations permit amateur radio experimentation within the 275–3,000 GHz range or at even higher frequencies on a national basis, under license conditions that are usually based on RR5.565 of the ITU Radio Regulations. Amateur radio operators utilizing submillimeter frequencies often attempt to set two-way communication distance records. In the United States, WA1ZMS and W4WWQ set a record of 1.42 kilometres (0.88 mi) on 403 GHz using CW (Morse code) on 21 December 2004. In Australia, at 30 THz a distance of 60 metres (200 ft) was achieved by stations VK3CV and VK3LN on 8 November 2020.

Manufacturing

Many possible uses of terahertz sensing and imaging are proposed in manufacturing, quality control, and process monitoring. These in general exploit the traits of plastics and cardboard being transparent to terahertz radiation, making it possible to inspect packaged goods. The first imaging system based on optoelectronic terahertz time-domain spectroscopy were developed in 1995 by researchers from AT&T Bell Laboratories and was used for producing a transmission image of a packaged electronic chip. This system used pulsed laser beams with duration in range of picoseconds. Since then commonly used commercial/ research terahertz imaging systems have used pulsed lasers to generate terahertz images. The image can be developed based on either the attenuation or phase delay of the transmitted terahertz pulse.

Since the beam is scattered more at the edges and also different materials have different absorption coefficients, the images based on attenuation indicates edges and different materials inside of objects. This approach is similar to X-ray transmission imaging, where images are developed based on attenuation of the transmitted beam.

In the second approach, terahertz images are developed based on the time delay of the received pulse. In this approach, thicker parts of the objects are well recognized as the thicker parts cause more time delay of the pulse. Energy of the laser spots are distributed by a Gaussian function. The geometry and behavior of Gaussian beam in the Fraunhofer region imply that the electromagnetic beams diverge more as the frequencies of the beams decrease and thus the resolution decreases. This implies that terahertz imaging systems have higher resolution than scanning acoustic microscope (SAM) but lower resolution than X-ray imaging systems. Although terahertz can be used for inspection of packaged objects, it suffers from low resolution for fine inspections. X-ray image and terahertz images of an electronic chip are brought in the figure on the right. Obviously the resolution of X-ray is higher than terahertz image, but X-ray is ionizing and can be impose harmful effects on certain objects such as semiconductors and live tissues.

To overcome low resolution of the terahertz systems near-field terahertz imaging systems are under development. In nearfield imaging the detector needs to be located very close to the surface of the plane and thus imaging of the thick packaged objects may not be feasible. In another attempt to increase the resolution, laser beams with frequencies higher than terahertz are used to excite the p-n junctions in semiconductor objects, the excited junctions generate terahertz radiation as a result as long as their contacts are unbroken and in this way damaged devices can be detected. In this approach, since the absorption increases exponentially with the frequency, again inspection of the thick packaged semiconductors may not be doable. Consequently, a tradeoff between the achievable resolution and the thickness of the penetration of the beam in the packaging material should be considered.

THz gap research

Ongoing investigation has resulted in improved emitters (sources) and detectors, and research in this area has intensified. However, drawbacks remain that include the substantial size of emitters, incompatible frequency ranges, and undesirable operating temperatures, as well as component, device, and detector requirements that are somewhere between solid state electronics and photonic technologies.

Free-electron lasers can generate a wide range of stimulated emission of electromagnetic radiation from microwaves, through terahertz radiation to X-ray. However, they are bulky, expensive and not suitable for applications that require critical timing (such as wireless communications). Other sources of terahertz radiation which are actively being researched include solid state oscillators (through frequency multiplication), backward wave oscillators (BWOs), quantum cascade lasers, and gyrotrons.

Safety

The terahertz region is between the radio frequency region and the laser optical region. Both the IEEE C95.1–2005 RF safety standard and the ANSI Z136.1–2007 Laser safety standard have limits into the terahertz region, but both safety limits are based on extrapolation. It is expected that effects on biological tissues are thermal in nature and, therefore, predictable by conventional thermal models . Research is underway to collect data to populate this region of the spectrum and validate safety limits.

A theoretical study published in 2010 and conducted by Alexandrov et al at the Center for Nonlinear Studies at Los Alamos National Laboratory in New Mexico created mathematical models predicting how terahertz radiation would interact with double-stranded DNA, showing that, even though involved forces seem to be tiny, nonlinear resonances (although much less likely to form than less-powerful common resonances) could allow terahertz waves to "unzip double-stranded DNA, creating bubbles in the double strand that could significantly interfere with processes such as gene expression and DNA replication". Experimental verification of this simulation was not done. Swanson's 2010 theoretical treatment of the Alexandrov study concludes that the DNA bubbles do not occur under reasonable physical assumptions or if the effects of temperature are taken into account. A bibliographical study published in 2003 reported that T-ray intensity drops to less than 1% in the first 500 μm of skin but stressed that "there is currently very little information about the optical properties of human tissue at terahertz frequencies".