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Through Electric current, Energy conservation and Michael Faraday

Fluorescent lamp fixtures are more costly than incandescent lamps because, among other things, they require a ballast to regulate current through the lamp, but the initial cost is offset by a much lower running cost. Compact fluorescent lamps (CFL) made in the same sizes as incandescent lamp bulbs are used as an energy-saving alternative to incandescent lamps in homes.

In the United States, fluorescent lamps are classified as universal waste. The United States Environmental Protection Agency recommends that fluorescent lamps be segregated from general waste for recycling or safe disposal, and some jurisdictions require recycling of them.

History

Physical discoveries

Fluorescence

The fluorescence of certain rocks and other substances had been observed for hundreds of years before its nature was understood. One of the first to explain it was Irish scientist Sir George Stokes from the University of Cambridge in 1852, who named the phenomenon "fluorescence" after fluorite, a mineral many of whose samples glow strongly because of impurities.

Discharge tubes

By mid-19th century, experimenters had observed a radiant glow emanating from partially evacuated glass vessels through which an electric current passed. The explanation relied on the nature of electricity and light phenomena as developed by the British scientists Michael Faraday in the 1840s and James Clerk Maxwell in the 1860s.

Little more was done with this phenomenon until 1856 when German glassblower Heinrich Geissler created a mercury vacuum pump that evacuated a glass tube to an extent not previously possible. Geissler invented the first gas-discharge lamp, the Geissler tube, consisting of a partially evacuated glass tube with a metal electrode at either end. When a high voltage was applied between the electrodes, the inside of the tube illuminated with a glow discharge. By putting different chemicals inside, the tubes could be made to produce a variety of colors, and elaborate Geissler tubes were sold for entertainment. More important was its contribution to scientific research. One of the first scientists to experiment with a Geissler tube was Julius Plücker, who systematically described in 1858 the luminescent effects that occurred in a Geissler tube. He also made the important observation that the glow in the tube shifted position when in proximity to an electromagnetic field. Alexandre Edmond Becquerel observed in 1859 that certain substances gave off light when they were placed in a Geissler tube. He went on to apply thin coatings of luminescent materials to the surfaces of these tubes. Fluorescence occurred, but the tubes were inefficient and had a short operating life.

Inquiries that began with the Geissler tube continued as better vacuums were produced. The most famous was the evacuated tube used for scientific research by William Crookes. That tube was evacuated by the highly effective mercury vacuum pump created by Hermann Sprengel. Research conducted by Crookes and others ultimately led to the discovery of the electron in 1897 by J. J. Thomson and X-rays in 1895 by Wilhelm Röntgen. The Crookes tube, as it came to be known, produced little light because the vacuum in it was too great and thus lacked the trace amounts of gas that are needed for electrically stimulated luminescence.

Early discharge lamps

Thomas Edison briefly pursued fluorescent lighting for its commercial potential. He invented a fluorescent lamp in 1896 that used a coating of calcium tungstate as the fluorescing substance, excited by X-rays. Although it received a patent in 1907, it was not put into production. As with a few other attempts to use Geissler tubes for illumination, it had a short operating life, and given the success of the incandescent light, Edison had little reason to pursue an alternative means of electrical illumination. Nikola Tesla made similar experiments in the 1890s, devising high-frequency powered fluorescent bulbs that gave a bright greenish light, but as with Edison's devices, no commercial success was achieved.

One of Edison's former employees created a gas-discharge lamp that achieved a measure of commercial success. In 1895 Daniel McFarlan Moore demonstrated lamps 2 to 3 meters (6.6 to 9.8 ft) in length that used carbon dioxide or nitrogen to emit white or pink light, respectively. They were considerably more complicated than an incandescent bulb, requiring both a high-voltage power supply and a pressure-regulating system for the fill gas.

Moore invented an electromagnetically controlled valve that maintained a constant gas pressure within the tube, to extend the working life. Although Moore's lamp was complicated, expensive, and required very high voltages, it was considerably more efficient than incandescent lamps, and it produced a closer approximation to natural daylight than contemporary incandescent lamps. From 1904 onwards Moore's lighting system was installed in a number of stores and offices. Its success contributed to General Electric's motivation to improve the incandescent lamp, especially its filament. GE's efforts came to fruition with the invention of a tungsten-based filament. The extended lifespan and improved efficacy of incandescent bulbs negated one of the key advantages of Moore's lamp, but GE purchased the relevant patents in 1912. These patents and the inventive efforts that supported them were of considerable value when the firm took up fluorescent lighting more than two decades later.

At about the same time that Moore was developing his lighting system, Peter Cooper Hewitt invented the mercury-vapor lamp, patented in 1901 (US 682692). Hewitt's lamp glowed when an electric current was passed through mercury vapor at a low pressure. Unlike Moore's lamps, Hewitt's were manufactured in standardized sizes and operated at low voltages. The mercury-vapor lamp was superior to the incandescent lamps of the time in terms of energy efficiency, but the blue-green light it produced limited its applications. It was, however, used for photography and some industrial processes.

Mercury vapor lamps continued to be developed at a slow pace, especially in Europe. By the early 1930s they received limited use for large-scale illumination. Some of them employed fluorescent coatings, but these were used primarily for color correction and not for enhanced light output. Mercury vapor lamps also anticipated the fluorescent lamp in their incorporation of a ballast to maintain a constant current.

Cooper-Hewitt had not been the first to use mercury vapor for illumination, as earlier efforts had been mounted by Way, Rapieff, Arons, and Bastian and Salisbury. Of particular importance was the mercury-vapor lamp invented by Küch and Retschinsky in Germany. The lamp used a smaller bore bulb and higher current operating at higher pressures. As a consequence of the current, the bulb operated at a higher temperature which necessitated the use of a quartz bulb. Although its light output relative to electrical consumption was better than that of other sources of light, the light it produced was similar to that of the Cooper-Hewitt lamp in that it lacked the red portion of the spectrum, making it unsuitable for ordinary lighting. Due to difficulties in sealing the electrodes to the quartz, the lamp had a short life.

Neon lamps

The next step in gas-based lighting took advantage of the luminescent qualities of neon, an inert gas that had been discovered in 1898 by isolation from the atmosphere. Neon glowed a brilliant red when used in Geissler tubes. By 1910, Georges Claude, a Frenchman who had developed a technology and a successful business for air liquefaction, was obtaining enough neon as a byproduct to support a neon lighting industry. While neon lighting was used around 1930 in France for general illumination, it was no more energy-efficient than conventional incandescent lighting. Neon tube lighting, which also includes the use of argon and mercury vapor as alternative gases, came to be used primarily for eye-catching signs and advertisements. Neon lighting was relevant to the development of fluorescent lighting, however, as Claude's improved electrode (patented in 1915) overcame "sputtering", a major source of electrode degradation. Sputtering occurred when ionized particles struck an electrode and tore off bits of metal. Although Claude's invention required electrodes with a lot of surface area, it showed that a major impediment to gas-based lighting could be overcome.

The development of the neon light also was significant for the last key element of the fluorescent lamp, its fluorescent coating. In 1926 Jacques Risler received a French patent for the application of fluorescent coatings to neon light tubes. The main use of these lamps, which can be considered the first commercially successful fluorescents, was for advertising, not general illumination. This, however, was not the first use of fluorescent coatings; Becquerel had earlier used the idea and Edison used calcium tungstate for his unsuccessful lamp. Other efforts had been mounted, but all were plagued by low efficiency and various technical problems. Of particular importance was the invention in 1927 of a low-voltage "metal vapor lamp" by Friedrich Meyer, Hans-Joachim Spanner, and Edmund Germer, who were employees of a German firm in Berlin. A German patent was granted but the lamp never went into commercial production.

Commercialization of fluorescent lamps

All the major features of fluorescent lighting were in place at the end of the 1920s. Decades of invention and development had provided the key components of fluorescent lamps: economically manufactured glass tubing, inert gases for filling the tubes, electrical ballasts, long-lasting electrodes, mercury vapor as a source of luminescence, effective means of producing a reliable electrical discharge, and fluorescent coatings that could be energized by ultraviolet light. At this point, intensive development was more important than basic research.

In 1934, Arthur Compton, a renowned physicist and GE consultant, reported to the GE lamp department on successful experiments with fluorescent lighting at General Electric Co., Ltd. in Great Britain (unrelated to General Electric in the United States). Stimulated by this report, and with all of the key elements available, a team led by George E. Inman built a prototype fluorescent lamp in 1934 at General Electric's Nela Park (Ohio) engineering laboratory. This was not a trivial exercise; as noted by Arthur A. Bright, "A great deal of experimentation had to be done on lamp sizes and shapes, cathode construction, gas pressures of both argon and mercury vapor, colors of fluorescent powders, methods of attaching them to the inside of the tube, and other details of the lamp and its auxiliaries before the new device was ready for the public."

In addition to having engineers and technicians along with facilities for R&D work on fluorescent lamps, General Electric controlled what it regarded as the key patents covering fluorescent lighting, including the patents originally issued to Hewitt, Moore, and Küch. More important than these was a patent covering an electrode that did not disintegrate at the gas pressures that ultimately were employed in fluorescent lamps. Albert W. Hull of GE's Schenectady Research Laboratory filed for a patent on this invention in 1927, which was issued in 1931. General Electric used its control of the patents to prevent competition with its incandescent lights and probably delayed the introduction of fluorescent lighting by 20 years. Eventually, war production required 24-hour factories with economical lighting, and fluorescent lights became available.

While the Hull patent gave GE a basis for claiming legal rights over the fluorescent lamp, a few months after the lamp went into production the firm learned of a U.S. patent application that had been filed in 1927 for the aforementioned "metal vapor lamp" invented in Germany by Meyer, Spanner, and Germer. The patent application indicated that the lamp had been created as a superior means of producing ultraviolet light, but the application also contained a few statements referring to fluorescent illumination. Efforts to obtain a U.S. patent had met with numerous delays, but were it to be granted, the patent might have caused serious difficulties for GE. At first, GE sought to block the issuance of a patent by claiming that priority should go to one of their employees, Leroy J. Buttolph, who according to their claim had invented a fluorescent lamp in 1919 and whose patent application was still pending. GE also had filed a patent application in 1936 in Inman's name to cover the "improvements" wrought by his group. In 1939 GE decided that the claim of Meyer, Spanner, and Germer had some merit, and that in any event a long interference procedure was not in their best interest. They therefore dropped the Buttolph claim and paid $180,000 to acquire the Meyer, et al. application, which at that point was owned by a firm known as Electrons, Inc. The patent was duly awarded in December 1939. This patent, along with the Hull patent, put GE on what seemed to be firm legal ground, although it faced years of legal challenges from Sylvania Electric Products, Inc., which claimed infringement on patents that it held.

Even though the patent issue was not completely resolved for many years, General Electric's strength in manufacturing and marketing gave it a pre-eminent position in the emerging fluorescent light market. Sales of "fluorescent lumiline lamps" commenced in 1938 when four different sizes of tubes were put on the market. They were used in fixtures manufactured by three leading corporations: Lightolier, Artcraft Fluorescent Lighting Corporation, and Globe Lighting. The Slimline fluorescent ballast's public introduction in 1946 was by Westinghouse and General Electric and Showcase/Display Case fixtures were introduced by Artcraft Fluorescent Lighting Corporation in 1946. During the following year, GE and Westinghouse publicized the new lights through exhibitions at the New York World's Fair and the Golden Gate International Exposition in San Francisco. Fluorescent lighting systems spread rapidly during World War II as wartime manufacturing intensified lighting demand. By 1951 more light was produced in the United States by fluorescent lamps than by incandescent lamps.

In the first years zinc orthosilicate with varying content of beryllium was used as greenish phosphor. Small additions of magnesium tungstate improved the blue portion of the spectrum, yielding acceptable white. After the discovery that beryllium was toxic, halophosphate-based phosphors dominated.

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