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Thorium-based nuclear power

Nuclear energy extracted from thorium isotopes

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Through Nuclear fission, Isotope and Sustainable energy

Thorium was first used in a commercial reactor in 1962, at the Indian Point Energy Center. Since then, several other commercial reactors have been fueled using thorium, including light-water reactors and high-temperature gas-cooled reactors. The feasibility of a thorium fuel cycle at a large scale was demonstrated through the design, construction and successful operation of the thorium-based Light Water Breeder Reactor (LWBR) core installed at the Shippingport Atomic Power Station. The reactor of this power plant was designed to accommodate different cores. The thorium core was rated at 60 MW(e), produced power from 1977 through 1982 (producing over 2.1 billion kilowatt hours of electricity) and converted enough thorium-232 into uranium-233 to achieve a 1.014 breeding ratio. Indian heavy-water reactors have for a long time used thorium-bearing fuel alongside uranium and plutonium.

There was considerable interest in using thorium instead of uranium between the 1950s and 1970s, particularly in the United States and Germany, to supplement limited supplies of uranium. However, enthusiasm largely declined due to the discovery of large deposits of uranium. Worldwide interest in thorium fuel cycles picked up later due to interest in proliferation-resistant fuel cycles. Nuclear scientists Ralph W. Moir and Edward Teller suggested in 2005 that research on thorium-fueled molten-salt reactors should be restarted after a three-decade shutdown and that a small prototype plant should be built. Other countries have made commercial plans for thorium-based power plants on a national scale. In 2024, the Chinese TMSR-LF1 became the first operational molten-salt reactor to use thorium fuel.

In 2011, a group of scientists at the Georgia Institute of Technology assessed thorium-fueled molten-salt reactors as "a 1000+ year solution or a quality low-carbon bridge to truly sustainable energy sources solving a huge portion of mankind's negative environmental impact."

History

The use of thorium to breed uranium-233 (233U) was first discovered in 1940 by Glenn Seaborg, from the neutron bombardment of thorium in a cyclotron. During the Manhattan Project, after the construction of the X-10 Graphite Reactor, Seaborg quickly realized the potential of uranium-233 as a fissile material. Research continued throughout the Manhattan Project; however, it was largely sidelined in the weapons program in favor of plutonium. Following the end of the war, the weapons production reactors at the Hanford Site were loaded with thorium slugs to breed 233U. At Oak Ridge, work continued on separation of 233U for both military and civilian applications.

The newly-formed Atomic Energy Commission (AEC) began exploring the feasibility of commercial nuclear power. By this point, pressurized water reactors (PWRs) using enriched uranium were being developed by the AEC's Naval Reactors division for use in propelling nuclear submarines. In 1954, the AEC began a five-year power reactor development program to explore reactors suitable for commercial electricity generation. In March 1954, the AEC's Subcommittee on Research and Development presented the Commission with a report on kickstarting a commercial nuclear industry. The subcommittee identified five reactor concepts for development, including the PWR, Sodium Graphite Reactor, boiling water reactor, fast breeder reactor, and homogeneous reactor. The homogeneous reactor, which was to be a thorium-fueled thermal breeder reactor, was judged as the most promising reactor concept for economic nuclear power due to its simple design, lack of fuel fabrication, and ease of extracting 233U. The sodium graphite reactor concept was also examined for its ability to function as a thorium breeder reactor.

The AEC then proposed to build demonstration reactors for each concept, including the Shippingport Atomic Power Station (PWR), Sodium Reactor Experiment (SGR), Experimental Boiling Water Reactor (BWR), Experimental Breeder Reactor II (FBR), and Homogeneous Reactor Experiment II (HR). The AEC also proposed an additional, larger demonstration plant for the homogeneous thorium concept, tentatively called the Homogeneous Thorium Reactor (HTR), which was to demonstrate the breeding of 233U in a commercial plant. The 16 MWe HTR was expected to begin operation in 1959. Westinghouse and the Pennsylvania Power & Light Company initiated studies in 1955 and proposed a prototype power plant in 1959, however the plant was not constructed.

The first commercial nuclear plant to use thorium in its fuel was Indian Point Unit 1, which went critical in August 1962. Indian Point was built to demonstrate the thorium fuel cycle in a commercial reactor and was fueled with a mixture of thorium and highly-enriched uranium (HEU). In fact, the plant was originally referred to as the Consolidated Edison Thorium Reactor. However, the high cost of the HEU fuel combined with the high cost of thorium reprocessing led the operator, Consolidated Edison, to switch to low-enriched uranium instead. The high cost of thorium reprocessing was described as a "financial disaster", and the thorium core was instead disposed of as waste without significant reprocessing.

In 1963, Naval Reactors had proposed the use of a seed-blanket core to allow light-water reactors to run on a thorium fuel cycle. Such reactors would be capable of highly efficient fuel utilization, including the prospect of breeding. By 1964, concerns over the supply of nuclear fuel led the AEC to prioritize improved utilization of uranium and thorium. The AEC began an advanced converters program, which identified the heavy-water reactor, high-temperature gas-cooled reactor (HTGR), thorium seed-blanket LWR, and SGR as desirable concepts. The advanced converters program was later focused on development of a thorium-fueled, heavy-water organic-cooled reactor (HWOCR), however research on both the HTGR and seed-blanket reactor continued. The HWOCR was a joint project with Atomic Energy of Canada Limited. It was cancelled in 1967, as the AEC shifted its focus towards breeder plants.

The AEC promoted the construction of high-temperature gas-cooled reactors fueled with thorium and 233U. The first such reactor, Peach Bottom Unit 1, used a thorium-HEU mixture. It served as a prototype for the later Fort Saint Vrain Nuclear Power Plant. Fort Saint Vrain, which used similar thorium fuel, was plagued with unrelated operational issues that led to its early closure. The Fort Saint Vrain plant was intended as a demonstration of future 1000 MWe thorium fuel cycle plants with the possibility of operating as thorium breeders. Several utilities had placed orders with General Atomics to build several of these large reactors. However, financial issues in the utility industry caused these plants to be cancelled.

The AEC used the weapons production reactors at Hanford to breed significant quantities of 233U from thorium for use in both nuclear weapons and for civilian research. Several tons of uranium-233 were bred from thorium in AEC reactors, some of which was processed at the Rocky Flats Plant. Uranium-233 was used in the MET shot of the Operation Teapot series of nuclear tests. According to Chuck Hansen, uranium-233 was evaluated for its potential in substituting for supergrade plutonium in nuclear weapons, however it was deemed as equivalent to plutonium in its usefulness. The further refinement of weapon designs, in particular the use of boosted fission weapons that did not require such high-grade plutonium, curtailed military interest in 233U. Several 233U-based nuclear weapons were tested by the United States between 1955 and 1968.

The aqueous homogeneous thorium reactor concept was abandoned by the AEC in the early 1960s in favor of the related molten-salt reactor design. The AEC funded the construction of the Molten-Salt Reactor Experiment, a prototype molten salt reactor, using uranium-233 fuel. The MSRE reactor, built at Oak Ridge National Laboratory, operated critical for roughly 15,000 hours from 1965 to 1969 (at a power level somewhat under 8 MWth). In 1968, Glenn Seaborg, the chairman of the AEC, publicly announced that a 233U-based reactor had been successfully developed and tested. For its final year of operation, the reactor was briefly fueled with plutonium fluoride. The project's leaders also proposed a test run using plutonium fuel, however this was never carried out due to the project's cancellation. In 1969, Seaborg publicly proclaimed that, "...someday the world will have commercial power reactors of both the uranium-plutonium and the thorium-uranium types".

In 1970, the AEC's Division of Technical Information published a booklet, Thorium and the Third Fuel, as part of its Understanding the Atom educational series aimed at increasing public understanding of nuclear energy. The booklet stated that thorium was unlikely to replace uranium-235 or plutonium as the principal reactor fuel, but predicted that several reactors were likely to be developed using it. It highlighted the molten-salt breeder reactor as perhaps "...the most exciting of all prospects for using thorium".

Despite the project's apparent success, the MSRE was shut down in December 1969 due to pressure from Milton Shaw, the director of the AEC's Reactor Development and Testing Division. At the time, the US government was heavily interested in breeder reactors to meet the projected need for nuclear fuel. Shaw pressured the MSRE team, led by Oak Ridge director Alvin Weinberg, to end the project due to his preference for the other competing breeder design at the time, the liquid metal fast breeder reactor.

By 1973, due to Shaw's influence, the US government had essentially settled on uranium technology and largely discontinued thorium-related nuclear research. The reasons were that uranium-fueled reactors were considered more efficient, the research into uranium was proven and thorium's breeding ratio was thought insufficient to produce enough fuel to support development of a commercial nuclear industry. As Moir and Teller later wrote, "The competition came down to a liquid metal fast breeder reactor (LMFBR) on the uranium-plutonium cycle and a thermal reactor on the thorium-233U cycle, the molten salt breeder reactor. The LMFBR had a larger breeding rate ... and won the competition." In their opinion, the decision to stop development of thorium reactors, at least as a backup option, "was an excusable mistake". The government pushed ahead with the LMFBR design with the Clinch River Breeder Reactor Project starting in 1970, however the project encountered substantial political opposition and was finally cancelled in 1983.

In 2009, science writer Richard Martin claimed that Weinberg, who was director at Oak Ridge and primarily responsible for the MSRE, lost his job as director because he championed development of thorium reactors. At the time, Martin claimed that Weinberg's unwillingness to sacrifice potentially safe nuclear power for the benefit of military uses forced him to retire. However, in his 2012 book SuperFuel, Martin refuted the idea that thorium was rejected by the AEC because of the desire for weapons production:

The theory is now repudiated not only by more circumspect scientists like Jess Gehin, a senior program manager for reactor technology at Oak Ridge, but by many in the thorium movement. The evidence that Shaw and the AEC killed the MSBR specifically because it wasn't an efficient producer of weapons-grade plutonium is thin. But that misses the point.

Others, including nuclear engineer Nick Touran, have agreed that thorium was not deprioritized due to a focus on weaponization. Touran wrote that "when MSRs were finally given their chance in the 1950s and 60s, their (non-existent) inability to make bombs was not to blame for the cancellation". Touran also called out Martin's 2009 article for promoting this myth. Similarly, Jess Gehin, a senior manager at Oak Ridge and professor at the University of Tennessee, criticized Martin's book SuperFuel for confusing the benefits of the liquid fluoride thorium reactor design with benefits intrinsic to thorium itself and for many incorrect technical claims.

Even after the cancellation of the MSRE, thorium research continued. Admiral Hyman Rickover, the developer of naval nuclear propulsion and head of the US Naval Reactors office, had pushed for a thorium-fueled breeder project since 1963 and organized the construction of a light-water breeder reactor (LWBR) project. First reaching criticality on August 26, 1977, this project successfully turned the Shippingport Atomic Power Station, the first peacetime nuclear power plant, into a demonstration 232Th−233U breeder reactor. After successful operation until 1982, the reactor was found to have a breeding ratio of 1.4%.

In Germany, the AVR pebble-bed reactor utilized mixed-oxide 235U−232Th TRISO fuel, and operated from 1967 until 1988. Based on the AVR design, the Thorium High-Temperature Reactor (THTR-300), a 300MWe commercial reactor was constructed and commenced operation in 1985. However, both reactors were plagued with design issues. THTR-300 was shut down in 1989, after only four years of operation.

In the Netherlands, the KEMA laboratories operated an experimental aqueous homogeneous reactor called the KEMA Suspension Test Reactor (KSTR). The 1 MWth KSTR was composed of 5 μm thorium and highly-enriched uranium oxide particles suspended in light water. It was designed as a test reactor for thorium-cycle AHR power plants.

Despite the documented history of thorium nuclear power, and successful demonstration of thorium-based breeding by the operation of the LWBR core at Shippingport, by 2009 many nuclear experts were nonetheless unaware of it. According to Chemical & Engineering News, "most people—including scientists—have hardly heard of the heavy-metal element and know little about it", noting a comment by a conference attendee that "it's possible to have a Ph.D. in nuclear reactor technology and not know about thorium energy."

Others, including former NASA scientist and prominent thorium advocate Kirk Sorensen, agree that "thorium was the alternate path". According to Sorensen, during a documentary interview, he states that if the US had not discontinued its research in 1974 it could have "probably achieved energy independence by around 2000".

On 18 May 2022, US Senator Tommy Tuberville introduced US Senate bill S.4242 – "A bill to provide for the preservation and storage of uranium-233 to foster development of thorium molten-salt reactors", the 'Thorium Energy Security Act'. However, it was not adopted by Congress.

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