Heat engine

Examples

Although some cycles have a typical combustion location (internal or external), they can often be implemented with the other. For example, John Ericsson developed an external heated engine running on a cycle very much like the earlier Diesel cycle. In addition, externally heated engines can often be implemented in open or closed cycles. In a closed cycle the working fluid is retained within the engine at the completion of the cycle whereas in an open cycle the working fluid is either exchanged with the environment together with the products of combustion in the case of the internal combustion engine or simply vented to the environment in the case of external combustion engines like steam engines and turbines.

Everyday examples

Everyday examples of heat engines include the thermal power station, internal combustion engine, firearms, refrigerators and heat pumps. Power stations are examples of heat engines run in a forward direction in which heat flows from a hot reservoir and flows into a cool reservoir to produce work as the desired product. Refrigerators, air conditioners and heat pumps are examples of heat engines that are run in reverse, i.e. they use work to take heat energy at a low temperature and raise its temperature in a more efficient way than the simple conversion of work into heat (either through friction or electrical resistance). Refrigerators remove heat from within a thermally sealed chamber at low temperature and vent waste heat at a higher temperature to the environment and heat pumps take heat from the low temperature environment and 'vent' it into a thermally sealed chamber (a house) at higher temperature.

In general heat engines exploit the thermal properties associated with the expansion and compression of gases according to the gas laws or the properties associated with phase changes between gas and liquid states.

Earth's heat engine

Earth's atmosphere and hydrosphere—Earth's heat engine—are coupled processes that constantly even out solar heating imbalances through evaporation of surface water, convection, rainfall, winds and ocean circulation, when distributing heat around the globe.

A Hadley cell is an example of a heat engine. It involves the rising of warm and moist air in the earth's equatorial region and the descent of colder air in the subtropics creating a thermally driven direct circulation, with consequent net production of kinetic energy.

Phase-change cycles

In phase change cycles and engines, the working fluids are gases and liquids. The engine converts the working fluid from a gas to a liquid, from liquid to gas, or both, generating work from the fluid expansion or compression.

• Rankine cycle (classical steam engine)
• Regenerative cycle (steam engine more efficient than Rankine cycle)
• Organic Rankine cycle (Coolant changing phase in temperature ranges of ice and hot liquid water)
• Vapor to liquid cycle (drinking bird, injector, Minto wheel)
• Liquid to solid cycle (frost heaving – water changing from ice to liquid and back again can lift rock up to 60 cm.)
• Solid to gas cycle (firearms – solid propellants combust to hot gases.)

Gas-only cycles

In these cycles and engines the working fluid is always a gas (i.e., there is no phase change):

• Carnot cycle (Carnot heat engine)
• Ericsson cycle (Caloric Ship John Ericsson)
• Stirling cycle (Stirling engine, thermoacoustic devices)
• Internal combustion engine (ICE):
  • Otto cycle (e.g. gasoline/petrol engine)
  • Diesel cycle (e.g. Diesel engine)
  • Atkinson cycle (Atkinson engine)
  • Brayton cycle or Joule cycle originally Ericsson cycle (gas turbine)
  • Lenoir cycle (e.g., pulse jet engine)
  • Miller cycle (Miller engine)

Liquid-only cycles

In these cycles and engines the working fluid are always like liquid:

• Stirling cycle (Malone engine)

Electron cycles

• Johnson thermoelectric energy converter
• Thermoelectric (Peltier–Seebeck effect)
• Thermogalvanic cell
• Thermionic emission
• Thermotunnel cooling

Magnetic cycles

• Thermo-magnetic motor (Tesla)

Cycles used for refrigeration

A domestic refrigerator is an example of a heat pump: a heat engine in reverse. Work is used to create a heat differential. Many cycles can run in reverse to move heat from the cold side to the hot side, making the cold side cooler and the hot side hotter. Internal combustion engine versions of these cycles are, by their nature, not reversible.

Refrigeration cycles include:

• Air cycle machine
• Gas-absorption refrigerator
• Magnetic refrigeration
• Stirling cryocooler
• Vapor-compression refrigeration
• Vuilleumier cycle

Evaporative heat engines

The Barton evaporation engine is a heat engine based on a cycle producing power and cooled moist air from the evaporation of water into hot dry air.

Mesoscopic heat engines

Mesoscopic heat engines are nanoscale devices that may serve the goal of processing heat fluxes and perform useful work at small scales. Potential applications include e.g. electric cooling devices. In such mesoscopic heat engines, work per cycle of operation fluctuates due to thermal noise. There is exact equality that relates average of exponents of work performed by any heat engine and the heat transfer from the hotter heat bath. This relation transforms the Carnot's inequality into exact equality. This relation is also a Carnot cycle equality

Efficiency

The efficiency of a heat engine relates how much useful work is output for a given amount of heat energy input.

From the laws of thermodynamics, after a completed cycle:

• ${\displaystyle W+Q={\mathrm{\Delta }}_{cycle}U=0}$

and therefore

• ${\displaystyle W=-Q=-(Q_c+Q_h)}$

where

• ${\displaystyle W=-\oint PdV}$ is the net work extracted from the engine in one cycle. (It is negative, in the IUPAC convention, since work is done by the engine.)
• ${\displaystyle Q_h>0}$ is the heat energy taken from the high temperature heat source in the surroundings in one cycle. (It is positive since heat energy is added to the engine.)
• ${\displaystyle Q_c=-|Q_c|<0}$ is the waste heat given off by the engine to the cold temperature heat sink. (It is negative since heat is lost by the engine to the sink.)

In other words, a heat engine absorbs heat energy from the high temperature heat source, converting part of it to useful work and giving off the rest as waste heat to the cold temperature heat sink.

In general, the efficiency of a given heat transfer process is defined by the ratio of "what is taken out" to "what is put in". (For a refrigerator or heat pump, which can be considered as a heat engine run in reverse, this is the coefficient of performance and it is ≥ 1.) In the case of an engine, one desires to extract work and has to put in heat ${\displaystyle Q_h}$, for instance from combustion of a fuel, so the engine efficiency is reasonably defined as $${\displaystyle \eta =\frac{|W|}{Q_h}=\frac{Q_h+Q_c}{Q_h}=1+\frac{Q_c}{Q_h}=1-\frac{|Q_c|}{Q_h}}$$

The efficiency is less than 100% because of the waste heat ${\displaystyle Q_c<0}$ unavoidably lost to the cold sink (and corresponding compression work put in) during the required recompression at the cold temperature before the power stroke of the engine can occur again.

The theoretical maximum efficiency of any heat engine depends only on the temperatures it operates between. This efficiency is usually derived using an ideal imaginary heat engine such as the Carnot heat engine, although other engines using different cycles can also attain maximum efficiency. Mathematically, after a full cycle, the overall change of entropy is zero:

$${\displaystyle \mathrm{\Delta }{S}_h+\mathrm{\Delta }{S}_c={\mathrm{\Delta }}_{cycle}S=0}$$

Note that ${\displaystyle \mathrm{\Delta }{S}_h}$ is positive because isothermal expansion in the power stroke increases the multiplicity of the working fluid while ${\displaystyle \mathrm{\Delta }{S}_c}$ is negative since recompression decreases the multiplicity. If the engine is ideal and runs reversibly, ${\displaystyle Q_h=T_h\mathrm{\Delta }{S}_h}$ and ${\displaystyle Q_c=T_c\mathrm{\Delta }{S}_c}$, and thus

$${\displaystyle Q_h/T_h+Q_c/T_c=0,}$$

which gives ${\displaystyle Q_c/Q_h=-T_c/T_h}$ and thus the Carnot limit for heat-engine efficiency, $${\displaystyle {\eta }_{\text{max}}=1-\frac{T_c}{T_h}}$$

where ${\displaystyle T_h}$ is the absolute temperature of the hot source and ${\displaystyle T_c}$ that of the cold sink, usually measured in kelvins.

The reasoning behind this being the maximal efficiency goes as follows. It is first assumed that if a more efficient heat engine than a Carnot engine is possible, then it could be driven in reverse as a heat pump. Mathematical analysis can be used to show that this assumed combination would result in a net decrease in entropy. Since, by the second law of thermodynamics, this is statistically improbable to the point of exclusion, the Carnot efficiency is a theoretical upper bound on the reliable efficiency of any thermodynamic cycle.

Empirically, no heat engine has ever been shown to run at a greater efficiency than a Carnot cycle heat engine.

Figure 2 and Figure 3 show variations on Carnot cycle efficiency with temperature. Figure 2 indicates how efficiency changes with an increase in the heat addition temperature for a constant compressor inlet temperature. Figure 3 indicates how the efficiency changes with an increase in the heat rejection temperature for a constant turbine inlet temperature.

Endo-reversible heat-engines

By its nature, any maximally efficient Carnot cycle must operate at an infinitesimal temperature gradient; this is because any transfer of heat between two bodies of differing temperatures is irreversible, therefore the Carnot efficiency expression applies only to the infinitesimal limit. The major problem is that the objective of most heat-engines is to output power, and infinitesimal power is seldom desired.

A different measure of ideal heat-engine efficiency is given by considerations of endoreversible thermodynamics, where the system is broken into reversible subsystems, but with non reversible interactions between them. A classical example is the Curzon–Ahlborn engine, very similar to a Carnot engine, but where the thermal reservoirs at temperature ${\displaystyle T_h}$ and ${\displaystyle T_c}$ are allowed to be different from the temperatures of the substance going through the reversible Carnot cycle: ${\displaystyle T_h^{\prime }}$ and ${\displaystyle T_c^{\prime }}$. The heat transfers between the reservoirs and the substance are considered as conductive (and irreversible) in the form ${\displaystyle d{Q}_{h,c}/dt=\alpha (T_{h,c}-T_{h,c}^{\prime })}$. In this case, a tradeoff has to be made between power output and efficiency. If the engine is operated very slowly, the heat flux is low, ${\displaystyle T\approx T^{\prime }}$ and the classical Carnot result is found $${\displaystyle \eta =1-\frac{T_c}{T_h},}$$ but at the price of a vanishing power output. If instead one chooses to operate the engine at its maximum output power, the efficiency becomes $${\displaystyle \eta =1-\sqrt{\frac{T_c}{T_h}}}$$ (Note: T must be specified in absolute units of temperature such as K or °R.)

This model does a better job of predicting how well real-world heat-engines can do (Callen 1985, see also endoreversible thermodynamics):

As shown, the Curzon–Ahlborn efficiency much more closely models that observed.

History

Heat engines have been known since antiquity but were only made into useful devices at the time of the industrial revolution in the 18th century. They continue to be developed today.

Enhancements

Engineers have studied the various heat-engine cycles to improve the amount of usable work they could extract from a given power source. The Carnot cycle limit cannot be reached with any gas-based cycle, but engineers have found at least two ways to bypass that limit and one way to get better efficiency without bending any rules:

1. Increase the temperature difference in the heat engine. The simplest way to do this is to increase the hot side temperature, which is the approach used in modern combined-cycle gas turbines. Unfortunately, physical limits (such as the melting point of the materials used to build the engine) and environmental concerns regarding NO_x production (if the heat source is combustion with ambient air) restrict the maximum temperature on workable heat-engines. Modern gas turbines run at temperatures as high as possible within the range of temperatures necessary to maintain acceptable NO_x output . Another way of increasing efficiency is to lower the output temperature. One new method of doing so is to use mixed chemical working fluids, then exploit the changing behavior of the mixtures. One of the most famous is the so-called Kalina cycle, which uses a 70/30 mix of ammonia and water as its working fluid. This mixture allows the cycle to generate useful power at considerably lower temperatures than most other processes.
2. Exploit the physical properties of the working fluid. The most common such exploitation is the use of water above the critical point (supercritical water). The behavior of fluids above their critical point changes radically, and with materials such as water and carbon dioxide it is possible to exploit those changes in behavior to extract greater thermodynamic efficiency from the heat engine, even if it is using a fairly conventional Brayton or Rankine cycle. A newer and very promising material for such applications is supercritical CO₂. SO₂ and xenon have also been considered for such applications. Downsides include issues of corrosion and erosion, the different chemical behavior above and below the critical point, the needed high pressures and – in the case of sulfur dioxide and to a lesser extent carbon dioxide – toxicity. Among the mentioned compounds xenon is least suitable for use in a nuclear reactor due to the high neutron absorption cross section of almost all isotopes of xenon, whereas carbon dioxide and water can also double as a neutron moderator for a thermal spectrum reactor.
3. Exploit the chemical properties of the working fluid. A fairly new and novel exploit is to use exotic working fluids with advantageous chemical properties. One such is nitrogen dioxide (NO₂), a toxic component of smog, which has a natural dimer as di-nitrogen tetraoxide (N₂O₄). At low temperature, the N₂O₄ is compressed and then heated. The increasing temperature causes each N₂O₄ to break apart into two NO₂ molecules. This lowers the molecular weight of the working fluid, which drastically increases the efficiency of the cycle. Once the NO₂ has expanded through the turbine, it is cooled by the heat sink, which makes it recombine into N₂O₄. This is then fed back by the compressor for another cycle. Such species as aluminium bromide (Al₂Br₆), NOCl, and Ga₂I₆ have all been investigated for such uses. To date, their drawbacks have not warranted their use, despite the efficiency gains that can be realized.

Heat engine processes

Each process is one of the following:

• isothermal (at constant temperature, maintained with heat added or removed from a heat source or sink)
• isobaric (at constant pressure)
• isometric/isochoric (at constant volume), also referred to as iso-volumetric
• adiabatic (no heat is added or removed from the system during adiabatic process)
• isentropic (reversible adiabatic process, no heat is added or removed during isentropic process)