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Oil shale in Estonia

Overview of the industry in Estonia

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Through Sedimentary rock, Mining and Raw material

Oil shale (Estonian: põlevkivi; literally 'burning rock') has been defined as a strategic energy resource in Estonia and the oil shale industry in Estonia is one of the most developed in the world. Historically, most of mined oil shale was used for electricity generation. Of all the oil shale fired power stations in the world, the two largest are in Estonia. Although its share decreased in the decade to 2022, direct and indirect use of oil shale still generates about half of Estonia's electricity. About half of mined oil shale is used to produce shale oil, a type of synthetic oil extracted from oil shale by pyrolysis, which is sufficient to keep Estonia as the second largest shale oil producer in the world after China. In addition, oil shale and its products are used in Estonia for district heating and as a feedstock material for the cement industry.

In the 18th and 19th centuries, Estonian oil shale was described by several scientists and used as a low-grade fuel. Its use in industry commenced in 1916. Production of shale oil began in 1921 and oil shale was first used to generate electrical power in 1924. Shortly thereafter, systematic research into oil shale and its products began, and in 1938 a department of mining was established at Tallinn Technical University. After World War II, Estonian oil shale gas was used in Saint Petersburg (then called Leningrad) and in northern cities in Estonia as a substitute for natural gas. Increased need for electricity in the north-west of the Soviet Union led to the construction of large oil shale-fired power stations. Oil shale extraction peaked in 1980. Subsequently, the launch of nuclear reactors in Russia, particularly the Leningrad Nuclear Power Station, reduced demand for electricity produced from oil shale, and, along with a post-Soviet restructuring of the industry in the 1990s, led to a decrease in oil shale mining. After decreasing for two decades, oil shale mining started to increase again at the beginning of the 21st century. Most oil-shale fuelled electricity generation is planned to be phased out by 2030.

The industry continues to have a serious impact on the environment producing ordinary and hazardous waste and greenhouse gas emissions, lowering groundwater levels, altering water circulation, and spoiling water quality. Leachates from waste heaps pollute surface and groundwater. Former and current oil shale mines cover about one percent of Estonia's territory.

Resource

Graptolitic argillite

Estonian graptolitic argillite (also known as dictyonema argillite, dictyonema oil shale, dictyonema shale or alum shale) is a marine-type of black shale, belonging to the marinite-type of oil shales. Although the name dictyonema argillite is widely used instead of graptolitic argillite, it is now considered a misnomer as the graptolite fossils in the rock, earlier considered dictyonemids, were reclassified during the 1980s as members of the genus Rhabdinopora.

Graptolitic argillite was formed some 480 million years ago during the Early Ordovician under a marine environment. In mainland Estonia, it occurs at the foot of the North Estonian Klint, ranging from the Pakri Peninsula to Narva in an area covering about 11,000 square kilometres (4,200 sq mi). When findings in the western Estonian islands are included, its extent increases to about 12,200 square kilometres (4,700 sq mi). The thickness of the layer varies from less than 0.5 metres (1 ft 8 in) to a maximum of 8 metres (26 ft) in western Estonia, and its depth below the surface varies from 10 to 90 metres (33 to 295 ft).

Resources of graptolitic argillite in Estonia have been estimated at 60–70 billion tonnes. Although resources of graptolitic argillite exceed that of kukersite, attempts to use it as an energy source have been unsuccessful due to its low calorific value and high sulfur content. Its organic content ranges from 10 to 20% and its sulfur content from 2 to 4%. Correspondingly, its calorific value is only 5–8 megajoules per kilogram (MJ/kg; 1,200–1,900 kcal/kg) and its Fischer Assay oil yield is 3–5%. However, the graptolitic argillite resource in Estonia contains a potential 2.1 billion tonnes of oil. In addition, it contains 5.67 million tonnes of uranium – making it one of the main potential sources of uranium in Europe – 16.53 million tonnes of zinc, and 12.76 million tonnes of molybdenum. There is as yet no economical and environmentally friendly technology to extract either the metals or the oil.

Kukersite

Kukersite is a light-brown marine-type Late Ordovician oil shale formed some 460 million years ago. It was named kuckers by the Baltic German geologist Carl Friedrich Schmidt in the mid-19th century, and kukersite by the Russian paleobotanist Mikhail Zalessky in 1916. The name reflects the German name for Kukruse Manor, where oil shale samples were obtained.

Kukersite deposits in Estonia are the world's second highest-grade oil shale deposits after the Australian torbanite. Its organic content varies from 15% to 55%, averaging over 40%. Correspondingly, its mean calorific value is 15 MJ/kg (3,600 kcal/kg). The conversion ratio of its organic content into usable energy (shale oil and oil shale gas) is between 65 and 67%, and its Fischer Assay oil yield is 30 to 47%.

The principal organic component of kukersite is telalginite, which originated from the fossil green alga Gloeocapsomorpha prisca, deposited in a shallow marine basin. Kukersite lies at depths of 7 to 170 metres (23 to 558 ft). The most significant kukersite deposits in Estonia – the Estonian and the Tapa – cover about 3,000 to 5,000 square kilometres (1,200 to 1,900 sq mi), and together with the Leningrad deposit (an extension of the Estonian) form the Baltic Oil Shale Basin. The Estonian deposit, which covers about 2,000 square kilometres (770 sq mi), is used industrially. It consists of 23 exploration and mining fields. The Tapa deposit is not accounted as a reserve due to its lower calorific value, which makes its extraction economically inexpedient. In northern Estonia there are 50 layers of kukersite; the six lowest of these form a 2.5-to-3-metre (8 ft 2 in to 9 ft 10 in) thick mineable bed. In this area kukersite lies near the surface. To the south and west it lies deeper and its thickness and quality decrease.

According to the International Energy Agency, Estonia's kukersite represents about 1.1% of global and 17% of European oil shale resources. The total kukersite resources in Estonia are estimated to be about 4.8 billion tonnes, including 1.3 billion tonnes of economically proven and probable reserves. Economically proven and probable reserves consist of mineable deposits with energy ratings of at least 35 gigajoules per square metre and calorific values of at least 8 MJ/kg, located in areas without environmental restrictions. Up to 650 million tonnes of economically proven and probable reserves are designated as recoverable.

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