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Particulate matter

Microscopic solid or liquid matter suspended in the Earth's atmosphere

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Size comparisons for PM particles
Environmental Protection Agency · Public domain

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Categories of atmospheric particles include inhalable coarse particles, designated PM10, which are particles of coarse granularity, with a particle diameter of 10 micrometers (μm) or less; fine particles, designated PM2.5, with a diameter of 2.5 μm or less; ultrafine particles, PM.10 with a diameter of 100 nanometers (nm) or less; and soot (fine or ultrafine particles primarily made up of carbon).

Airborne particulate matter is a IARC Group 1 carcinogen. Particulate matter is considered the most dangerous type of air pollution because particulates can penetrate deep into the lungs and travel through the blood stream to multiple organs, such as the brain. Particulate matter contributes to health problems such as stroke, cardiovascular disease, respiratory disease, many types of cancer, and preterm birth. It is associated with an increased risk of cognitive impairment. There is no safe level for exposure to particulates.

Worldwide, exposure to PM2.5 contributed to 7.9 million deaths in 2023; of those, 4.9 million had outdoor air pollution as a contributing factor, and 2.8 million had household air pollution as a contributing factor. Fine particulate matter (PM2.5) is considered the leading environmental risk factor for earlier death worldwide. Because many sources of particulates result from human actions, it is a modifiable risk factor which can be addressed. Many countries have established standards for particulate matter and are improving air quality.

Composition

The chemical composition of particulate matter (PM) in atmospheric aerosols varies widely with both time and space. It is affected by emission sources (both natural- and human-caused), geography, weather conditions, and chemical reactions. Atmospheric aerosols can change between liquid, solid, and semisolid states depending on conditions. The particulate matter in an aerosol can be described as primary (directly emitted) or secondary (formed through chemical reactions in the air). PM can include both organic and inorganic components such as minerals.

Both chemical composition and particle size and shape have effects on human health. Inhalable particles are often classified in terms of size as either coarse (PM10) with a diameter of 10 micrometers (μm) or less, or fine (PM2.5) with a diameter of 2.5 μm or less. Smaller particulates can penetrate deeper into the lungs and travel through the blood stream to reach other organs. Human-generated particulates are often smaller in size (e.g. PM2.5 or PM1), and pose significant threats to human health.

The chemical composition and size of particulates in an aerosol also determine how the aerosol interacts with solar radiation and affects climate. Chemical constituents within an aerosol change its overall refractive index, determining how much light is scattered or absorbed.

Mineral dust

Wind-blown mineral dust is a major component of particulate matter globally. Most sand and dust storms originate from a dust belt stretching from north Africa through the Middle East into Asia. Dust storms can also arise in arid areas of North and South America and Australia. Particles from dust storms can remain in the atmosphere and travel thousands of km from their source.

Mineral dust is a complex mixture that can be formed from quartz, feldspars, clays, calcites, iron oxides and other material blown from the Earth's crust. It often contains mineral oxides of major crustal elements such as aluminum (Al), silicon (Si), calcium (Ca), iron (Fe), and titanium (Ti). It can also contain alkali metals such as potassium (K), sodium (Na), and lithium (Li); alkaline earth metals such as magnesium (Mg); and heavy metals such as lead (Pb), copper (Cu), nickel (Ni), and zinc (Zn). Mineral dust in particulate matter is light-absorbing. Higher levels of lead in top soil and dust are associated with higher blood levels of lead in people.

Sea salt

Sea salt particles are another leading contributor to global particulate matter. Sea salt aerosols (SSAs) can develop over both open water and pack ice. Approximately 80% of the surface of the Southern Hemisphere is oceanic, and the average concentration of SSAs is generally higher there than in the Northern Hemisphere. The production of sea salt aerosols is affected by aspects of the air-sea interface including wind speed, seawater temperature, surface tension, density, and viscosity. Their distribution also varies with altitude, falling off rapidly at higher levels. Few sea-salt particles rise above the tropopause to reach the upper troposphere.

Sea salt aerosols reflect the composition of sea spray and evaporated sea water, consisting mainly of inorganic salts like sodium chloride (NaCl), along with magnesium, sulfate, calcium, bromine and potassium. Sea salt aerosols can include biological and organic matter such as bacteria, viruses, proteins, enzymes, dissolved organic carbon, fatty acids and sugars. SSA particles are key to the formation of clouds: hygroscopicity, the ability of an individual particle to take up water and eventually become a cloud droplet, is a function of particle size and composition. Sea salt aerosols affect climate both directly by scattering incoming solar radiation and indirectly through cloud formation. They are relatively large compared to other aerosols.

Organic matter

Organic matter (OM) contains carbon-based compounds, which can be either primary or secondary. Carbon combines with hydrogen and other elements to form complex molecules like carbohydrates, proteins, and DNA in living organisms. Burning of living or once-living matter, whether natural or human-caused, releases black carbon (BC) and organic carbon (OC), both of which are part of smoke and soot. Approximately 85% of the world's population lives in the Northern Hemisphere, where human activities are the dominant sources of organic matter and fine particulate matter (PM25).

Black carbon tends to be released at higher temperatures and contains mostly pure (elemental) carbon. Organic carbon contains additional materials and is more complex. Bioaerosols are a form of organic carbon, biological fragments of living microbial, fungal, animal, and plant sources. Microplastics are synthetic polymer chains that are carbon-based. Organic matter can influence the atmospheric radiation field by both scattering and absorption. Black carbon is the most strongly light-absorbing aerosol component, while organic carbon tends to be less absorptive, depending on its structure. In addition to carbon compounds, the burning of petroleum and oil also releases sulfur oxides and many other chemicals into the atmosphere.

Secondary organic aerosols

Secondary organic aerosols (SOA) are major components of PM2.5, small inhalable particulate matter that is linked to health problems. Secondary organic aerosols form when gaseous vapors in the atmosphere (e.g. SO2, NO and NO2, NH3, VOCs) react chemically to produce compounds that then form particles. Precursor gases may be anthropogenic (e.g. from biomass and fossil fuel combustion) or natural (e.g. from dust, forest fires, or sea salt aerosols) in origin. Aerosols can mix rapidly in ambient air, forming new chemical compounds as well as diluting their concentration with distance from an emissions source.

The smallest class of particulates, PM1 frequently contains sulfate, ammonium, and nitrate. Primary gases such as sulfur and nitrogen oxides can oxidize to form secondary particles of sulfuric acid (liquid) and nitric acid (gaseous). In the presence of ammonia, they often form ammonium salts such as ammonium sulfate and ammonium nitrate (both can be dry or in aqueous solution). Secondary sulfate and nitrate aerosols tend to reflect solar radiation, but their ability to scatter light is affected by water absorption.

Composition of wildfires and haze

Due to effects of climate change, wildfire seasons have become increasingly severe globally, producing large amounts of particulate matter that can spread over thousands of miles. Wildfire smoke contains high levels of PM2.5, carbon monoxide, carbon dioxide, heavy metals like lead, and PAHs, which combine to form secondary pollutants. Wildfire smoke particulate matter is more toxic than similar weights of PM from non-fire-related ambient air.

Haze, particulate matter that generally causes visual effects, tends to consist of sulfur dioxide, nitrogen oxides, carbon monoxide, mineral dust, and organic matter in dry air. The particles are hygroscopic due to the presence of sulfur, and SO2 is converted to sulfate when high humidity and low temperatures are present. This causes reduced visibility and red-orange-yellow colors.

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