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Air pollution

Presence of dangerous substances in the air

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Air pollution by brick factories. The sun can be seen in the background just above the factory chimney, partially covered by the chimney's smoke.
Janak Bhatta · CC BY-SA 4.0

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Outdoor air pollution comes from burning fossil fuels for electricity and transport, wildfires, some industrial processes, waste management, demolition and agriculture. Indoor air pollution is often from burning firewood or agricultural waste for cooking and heating. Other sources of air pollution include dust storms and volcanic eruptions. Many sources of local air pollution, especially burning fossil fuels, also release greenhouse gases that cause global warming. However, air pollution may limit warming locally.

Air pollution kills 7 to 8 million people each year. It is a significant risk factor for a number of diseases, including stroke, heart disease, chronic obstructive pulmonary disease (COPD), asthma, coronavirus and lung cancer. Particulate matter is the most deadly, both for indoor and outdoor air pollution. Ozone affects crops, and forests are damaged by the pollution that causes acid rain. Overall, the World Bank has estimated that welfare losses (premature deaths) and productivity losses (lost labor) caused by air pollution cost the world economy over $8 trillion per year.

Various technologies and strategies reduce air pollution. Key approaches include clean cookers, fire protection, improved waste management, dust control, industrial scrubbers, electric vehicles and renewable energy. National air quality laws have often been effective, notably the 1956 Clean Air Act in Britain and the 1963 US Clean Air Act. International efforts have had mixed results: the Montreal Protocol almost eliminated harmful ozone-depleting chemicals, while international action on climate change has been less successful.

Major pollutants

Air pollutants can be tiny solid or liquid particles dispersed in the air (called aerosols), or gases. Pollutants are classified as primary or secondary. Primary pollutants are produced directly by a source and remain in the same chemical form after they have been emitted into the atmosphere. Examples include carbon monoxide gas from car exhausts and sulfur dioxide from factories. Secondary pollutants are not emitted directly. Rather, they form in the air when primary pollutants react with each other or with other parts of the atmosphere. Ground-level ozone is one example of a secondary pollutant. Some pollutants may be both primary and secondary — both are emitted directly and formed from other primary pollutants.

Ammonia

Ammonia (NH
3) is emitted mainly by overuse of synthetic nitrogen fertilizers on farmland, and from manure and urine from livestock. At typical concentrations in the air, it is not harmful to health directly. However, ammonia can react with other pollutants in the air to form ammonium sulfate or nitrate salts, contributing to particulate matter pollution. Furthermore, when ammonia is deposited onto the soil, it can harm ecosystems via eutrophication.

Carbon dioxide

Carbon dioxide (CO2) is mainly emitted by the burning of fossil fuels. CO2 is sometimes called an air pollutant, because it is the main greenhouse gas responsible for climate change. Although the World Health Organization recognizes CO2 as a climate pollutant, it does not include the gas in its Air Quality Guidelines or set recommended targets for it. This question of terminology has practical consequences, for example, in determining whether the U.S. Clean Air Act (which is designed to improve air quality) is deemed to regulate CO2 emissions. The Inflation Reduction Act of 2022 amended the Clean Air Act to define CO2 from fossil fuel burning explicitly as an air pollutant.

Carbon monoxide

Carbon monoxide (CO) is a colorless, odorless, and toxic gas. It is a product of combustion of fuel such as natural gas, coal, or wood. In the past, emissions from vehicles were the main source of CO, but modern vehicles do not emit much of it. Now, wildfires and bonfires are the main source of outdoors CO. Indoors, CO is a larger problem and mainly comes from cooking and heating. In poorly ventilated spaces, CO can accumulate to dangerous levels, and exposure may cause people to lose consciousness and die. When CO is destroyed in the atmosphere, it can raise levels of CO2 and CH4.

Ground-level ozone

Ground-level ozone (O
3) is mostly created when NO
x and volatile organic compounds mix in the presence of sunlight. It can also form from carbon monoxide or methane. Due to the influence of temperature and sunlight on this reaction, high ozone levels are most common on hot summer afternoons. It is the main gas in photochemical smog.

O
3 can be harmful to human health, but also to some materials, forests, plants, and crops. Smog is a particular problem in big cities where it cannot easily be transported away by wind (e.g. cities built in valleys surrounded by mountains). When ground-level ozone is produced, it can linger in the air for days or weeks, and therefore be transported far from where it was first formed.

Nitrogen oxides

Nitrogen oxides (NO
x), particularly nitric oxide (NO), are mostly created by the burning of fossil fuels, and in lesser amounts by lightning. Nitrogen dioxide (NO
2) is formed from NO in a reaction with other atmospheric gases. NO and NO
2 can form acid rain, can form into a haze, and can cause nutrient pollution in water. NO
2 is a reddish-brown toxic gas with a strong odor, whereas NO is odorless and colorless.

Particulate matter

Particulate matter (PM), also known as particle pollution, includes all airborne substances that are not gases. It is a mix of microscopic solid particles or droplets suspended in a gas.

Particulate matter can contain a large variety of materials and chemical compounds including toxic substances, which can vary strongly in size. Coarse PM (PM10) is 10 micrometer (μm) or smaller in diameter, fine PM (PM2.5) is smaller than 2.5 μm, and ultrafine particles are 0.1 μm or smaller. Smaller particles pose more risk to health, as they can reach the bloodstream. A definitive link between fine particulate pollution and higher death rates in urban areas was established by the Harvard Six Cities study, published in 1993.

Sea spray, wildfires, volcanoes and dust storms are the main natural sources of PM. Meanwhile, human sources include the burning of biomass and fossil fuels, as well as road emissions and dust resuspension. Human PM is usually finer than natural PM. Most particulate matter is formed in the atmosphere from precursor gases. For instance, sulfate comes from SO
2, nitrate from NO
2, and ammonium is formed from ammonia. Soot on the other hand is directly emitted from combustion, and consists of black carbon and organic compounds. Particulate matter can have a cooling effect locally on the climate, as it reflects sunlight away from Earth's surface.

Sulfur dioxide

Sulfur dioxide (SO2), an acidic and corrosive gas, is produced mostly by burning crude oil and coal. These fossil fuels often contain sulfur compounds, and their combustion generates sulfur dioxide. In Europe and North America, SO2 is mostly found in areas with significant shipping and industry, as road traffic fuels are regulated. Smaller amounts of SO2 are released from smelting and volcanoes.

High concentrations of SO2 in the air generally also lead to the formation of other sulfur oxides (SOx). SOx can react with other compounds in the atmosphere to form small particles and contribute to particulate matter pollution. At high concentrations, gaseous SOx can harm plants by damaging leafs and decreasing growth. Further oxidation of SO2, mostly taking place in cloud droplets, forms sulfuric acid (H2SO4), which is one of the components of acid rain.

Volatile organic compounds

Volatile organic compounds (VOCs) are a class of carbon-based chemicals that exist as gases at room temperature, found both indoors and outdoors. They can cause photochemical smog and form aerosols impacting climate. The group includes methane, acetone, and toluene. Some can cause cancer, such as butadiene and benzene, with benzene being released from cigarette smoking. Methane is a greenhouse gas and the second-largest driver of global warming. Other VOCs contribute to climate warming because they help form ground-level ozone, a greenhouse gas.

Other pollutants

Some heavy metals can be bad for health. For instance, lead exposure can lead to learning disabilities in children. In the atmosphere, heavy metals can exist in different states, such as particles or gases. One of the forms of chromium can cause cancer. Mercury is harmful both as an element and in an organic compound. In the atmosphere, it comes mostly from cement production, coal burning, and incinerators.

Persistent organic pollutants (POPs) are organic compounds that are resistant to environmental degradation. They persist in the environment, are capable of long-range transmission, bioaccumulate in humans and animals, and biomagnify in food chains. The Stockholm Convention on Persistent Organic Pollutants identified pesticides and other POPs of concern. These include dioxins and furans which are created by waste combustion. POPs are usually either semi-volatile (gaseous only at higher temperatures) or non-volatile (emitted as particles). The harmful effects of the pesticide DDT, a POP, were popularized by Rachel Carson's 1962 book Silent Spring. PFASs and polycyclic aromatic hydrocarbons (PAHs) are other examples of POPs.

Chlorofluorocarbons (CFCs) are a group of compounds which harm the ozone layer. They were widely used in aerosol sprays, refrigerants, and fire suppression. Due to their chemical stability, CFCs persist in the atmosphere and eventually reach the stratosphere (the upper atmosphere). There, they break down under the impact of UV light, which releases chlorine. This in turn reacts with ozone, destroying it. As the ozone layer blocks harmful UV radiation from reaching the Earth's surface, its depletion leads to health risks such as skin ageing and skin cancer.

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