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Vehicle emissions control

Study of reducing the emissions produced by motor vehicles

  • 14 min read
  • 8 chapters

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Types of emissions

Emissions of many air pollutants have been shown to have variety of negative effects on public health and the natural environment. Emissions that are principal pollutants of concern include:

  • Hydrocarbons (HC) – A class of burned or partially burned fuel, hydrocarbons are toxins. Hydrocarbons are a major contributor to smog, which can be a major problem in urban areas. Prolonged exposure to hydrocarbons contributes to asthma, liver disease, lung disease, and cancer. Regulations governing hydrocarbons vary according to type of engine and jurisdiction; in some cases, "non-methane hydrocarbons" are regulated, while in other cases, "total hydrocarbons" are regulated. Technology for one application (to meet a non-methane hydrocarbon standard) may not be suitable for use in an application that has to meet a total hydrocarbon standard. Methane is not directly toxic, but is more difficult to break down in fuel vent lines and a charcoal canister is meant to collect and contain fuel vapors and route them either back to the fuel tank or, after the engine is started and warmed up, into the air intake to be burned in the engine.
  • Volatile organic compounds (VOCs) – Organic compounds which typically have a boiling point less than or equal to 250 °C; for example chlorofluorocarbons (CFCs) and formaldehyde.
  • Carbon monoxide (CO) – A product of incomplete combustion, inhaled carbon monoxide reduces the blood's ability to carry oxygen; overexposure (carbon monoxide poisoning) may be fatal. (Carbon monoxide persistently binds to hemoglobin, the oxygen-carrying chemical in red blood cells, where oxygen (O2) would temporarily bind. The bonding of CO excludes O2 and also reduces the ability of the hemoglobin to release already-bound oxygen, on both counts rendering the red blood cells ineffective. Recovery is by the slow release of bound CO and the body's production of new hemoglobin – a healing process – so full recovery from moderate to severe [but nonfatal] CO poisoning takes hours or days. Removing a person from a CO-poisoned atmosphere to fresh air stops the injury but does not yield prompt recovery, unlike the case where a person is removed from an asphyxiating atmosphere [i.e. one deficient in oxygen]. Toxic effects delayed by days are also common.)
  • Nitrogen oxides (NOx) – Generated when nitrogen in the air reacts with oxygen at the high temperature and pressure inside the engine. NOx is a precursor to smog and acid rain. NOx includes NO and NO2. NO2 is extremely reactive. NOx production is increased when an engine runs at its most efficient (i.e. hottest) operating point, so there tends to be a natural tradeoff between efficiency and control of NOx emissions. It is expected to be reduced drastically by use of emulsion fuels.
  • Particulate matter – Soot or smoke made up of particles in the micrometre size range: Particulate matter causes negative health effects, including but not limited to respiratory disease and cancer. Very fine particulate matter has been linked to cardiovascular disease.
  • Sulfur oxide (SOx) – A general term for oxides of sulfur, which are emitted from motor vehicles burning fuel containing sulfur. Reducing the level of fuel sulfur reduces the level of sulfur oxides emitted from the tailpipe.

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